Agapie, Theodor

Article from CaltechAUTHORS

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• Bruening, Meaghan A. and Xiong, Shuoyan, et el. (2023) α,ω-Diene Generation from Ethylene and Butadiene by Copolymer Upcycling; ACS Sustainable Chemistry & Engineering; Vol. 11; No. 27; 9918-9923; 10.1021/acssuschemeng.3c02569
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• Scott, Anna G. and Agapie, Theodor (2023) Synthesis of a Fe₃-Carbyne Motif by Oxidation of an Alkyl Ligated Iron-Sulfur (WFe₃S₃) Cluster; Journal of the American Chemical Society; Vol. 145; No. 1; 2-6; PMCID PMC10575540; 10.1021/jacs.2c04826
• Shoshani, Manar M. and Xiong, Shuoyan, et el. (2022) Phosphine-Phenoxide Nickel Catalysts for Ethylene/Acrylate Copolymerization: Olefin Coordination and Complex Isomerization Studies Relevant to the Mechanism of Catalysis; Organometallics; Vol. 41; No. 15; 2119-2131; 10.1021/acs.organomet.2c00241
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• Shiau, Angela A. and Lee, Heui Beom, et el. (2022) Mnᴵⱽ₄O₄ Model of the S₃ Intermediate of the Oxygen-Evolving Complex: Effect of the Dianionic Disiloxide Ligand; Inorganic Chemistry; 10.1021/acs.inorgchem.2c01612
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• Bailey, Gwendolyn A. and Buss, Joshua A., et el. (2021) Terminal, Open-Shell Mo Carbide and Carbyne Complexes: Spin Delocalization and Ligand Noninnocence; Journal of the American Chemical Society; Vol. 143; No. 33; 13091-13102; 10.1021/jacs.1c03806
• Bailey, Gwendolyn A. and Agapie, Theodor (2021) Terminal Mo Carbide and Carbyne Reactivity: H₂ Cleavage, B–C Bond Activation, and C–C Coupling; Organometallics; Vol. 40; No. 16; 2881-2887; 10.1021/acs.organomet.1c00336
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• Sampson, Jessica and Bruening, Meaghan, et el. (2021) Copolymerization of Ethylene and Long-Chain Functional α-Olefins by Dinuclear Zirconium Catalysts; Organometallics; Vol. 40; No. 12; 1854-1858; 10.1021/acs.organomet.1c00126
• Xiong, Shuoyan and Shoshani, Manar M., et el. (2021) Efficient Copolymerization of Acrylate and Ethylene with Neutral P, O-Chelated Nickel Catalysts: Mechanistic Investigations of Monomer Insertion and Chelate Formation; Journal of the American Chemical Society; Vol. 143; No. 17; 6516-6527; 10.1021/jacs.1c00566
• Thevenon, Arnaud and Rosas-Hernández, Alonso, et el. (2021) Dramatic HER Suppression on Ag Electrodes via Molecular Films for Highly Selective CO₂ to CO Reduction; ACS Catalysis; Vol. 11; No. 8; 4530-4537; 10.1021/acscatal.1c00338
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• Ribson, Ryan D. and Choi, Gyeongshin, et el. (2020) Controlling Singlet Fission with Coordination Chemistry-Induced Assembly of Dipyridyl Pyrrole Bipentacenes; ACS Central Science; Vol. 6; No. 11; 2088-2096; PMCID PMC7706079; 10.1021/acscentsci.0c01044
• Arnett, Charles H. and Bogacz, Isabel, et el. (2020) Mixed-Valent Diiron µ-Carbyne, µ-Hydride Complexes: Implications for Nitrogenase; Journal of the American Chemical Society; Vol. 142; No. 44; 18795-18813; 10.1021/jacs.0c05920
• Shoshani, Manar M. and Agapie, Theodor (2020) Ligand architecture for triangular metal complexes: a high oxidation state Ni₃ cluster with proximal metal arrangement; Chemical Communications; Vol. 56; No. 76; 11279-11282; 10.1039/d0cc03816d
• Ozden, Adnan and Li, Fengwang, et el. (2020) High-Rate and Efficient Ethylene Electrosynthesis Using a Catalyst/Promoter/Transport Layer; ACS Energy Letters; Vol. 5; No. 9; 2811-2818; 10.1021/acsenergylett.0c01266
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• Arnett, Charles H. and Agapie, Theodor (2020) Activation of an Open Shell, Carbyne-Bridged Diiron Complex Toward Binding of Dinitrogen; Journal of the American Chemical Society; Vol. 142; No. 22; 10059-10068; 10.1021/jacs.0c01896
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• Lee, Heui Beom and Agapie, Theodor (2019) Redox Tuning via Ligand-Induced Geometric Distortions at a YMn₃O₄ Cubane Model of the Biological Oxygen Evolving Complex; Inorganic Chemistry; Vol. 58; No. 22; 14998-15003; PMCID PMC6876925; 10.1021/acs.inorgchem.9b00510
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• Reed, Christopher J. and Agapie, Theodor (2019) A Terminal Fe^(III)-Oxo in a Tetranuclear Cluster: Effects of Distal Metal Centers on Structure and Reactivity; Journal of the American Chemical Society; Vol. 141; No. 24; 9479-9484; PMCID PMC7207158; 10.1021/jacs.9b03157
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• Reed, Christopher J. and Agapie, Theodor (2018) Thermodynamics of Proton and Electron Transfer in Tetranuclear Clusters with Mn–OH₂/OH Motifs Relevant to H₂O Activation by the Oxygen Evolving Complex in Photosystem II; Journal of the American Chemical Society; Vol. 140; No. 34; 10900-10908; PMCID PMC6277146; 10.1021/jacs.8b06426
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• Hirscher, Nathanael A. and Agapie, Theodor (2017) Stoichiometrically Activated Catalysts for Ethylene Tetramerization using Diphosphinoamine-Ligated Cr Tris(hydrocarbyl) Complexes; Organometallics; Vol. 36; No. 21; 4107-4110; 10.1021/acs.organomet.7b00706
• Reed, Christopher J. and Agapie, Theodor (2017) Tetranuclear Fe Clusters with a Varied Interstitial Ligand: Effects on the Structure, Redox Properties, and Nitric Oxide Activation; Inorganic Chemistry; Vol. 56; No. 21; 13360-13367; PMCID PMC6277142; 10.1021/acs.inorgchem.7b02114
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• Buss, Joshua A. and Agapie, Theodor (2016) Mechanism of Molybdenum-Mediated Carbon Monoxide Deoxygenation and Coupling: Mono- and Dicarbyne Complexes Precede C–O Bond Cleavage and C–C Bond Formation; Journal of the American Chemical Society; Vol. 138; No. 50; 16466-16477; 10.1021/jacs.6b10535
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• Henthorn, Justin T. and Agapie, Theodor (2016) Modulation of Proton-Coupled Electron Transfer through Molybdenum–Quinonoid Interactions; Inorganic Chemistry; Vol. 55; No. 11; 5337-5342; 10.1021/acs.inorgchem.6b00331
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• Horak, Kyle T. and Agapie, Theodor (2016) Dioxygen Reduction by a Pd(0)–Hydroquinone Diphosphine Complex; Journal of the American Chemical Society; Vol. 138; No. 10; 3443-3452; 10.1021/jacs.5b12928
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• Lin, Po-Heng and Takase, Michael K., et el. (2015) Investigations of the Effect of the Non-Manganese Metal in Heterometallic-Oxido Cluster Models of the Oxygen Evolving Complex of Photosystem II: Lanthanides as Substitutes for Calcium; Inorganic Chemistry; Vol. 54; No. 1; 59-64; PMCID PMC4286168; 10.1021/ic5015219
• Tsui, Emily Y. and Agapie, Theodor (2014) Carbon dioxide cleavage by a Ni_2 complex supported by a binucleating bis(N-heterocyclic carbene) framework; Polyhedron; Vol. 84; 103-110; PMCID PMC6214461; 10.1016/j.poly.2014.06.041
• Martin-Diaconescu, Vlad and Gennari, Marcello, et el. (2014) Ca K‑Edge XAS as a Probe of Calcium Centers in Complex Systems; Inorganic Chemistry; Vol. 54; No. 4; 1283-1292; PMCID PMC4331723; 10.1021/ic501991e
• Henthorn, Justin T. and Agapie, Theodor (2014) Dioxygen Reactivity with a Ferrocene–Lewis Acid Pairing: Reduction to a Boron Peroxide in the Presence of Tris(pentafluorophenyl)borane; Angewandte Chemie International Edition; Vol. 53; No. 47; 12893-12896; 10.1002/anie.201408462
• Kanady, Jacob S. and Lin, Po-Heng, et el. (2014) Toward Models for the Full Oxygen-Evolving Complex of Photosystem II by Ligand Coordination To Lower the Symmetry of the Mn_3CaO_4 Cubane: Demonstration That Electronic Effects Facilitate Binding of a Fifth Metal; Journal of the American Chemical Society; Vol. 136; No. 41; 14373-14376; PMCID PMC4210109; 10.1021/ja508160x
• Lionetti, Davide and Agapie, Theodor (2014) How calcium affects oxygen formation; Nature; Vol. 513; No. 7519; 495-496; PMCID PMC4879831; 10.1038/nature13753
• Buss, Joshua A. and Edouard, Guy A., et el. (2014) Molybdenum Catalyzed Ammonia Borane Dehydrogenation: Oxidation State Specific Mechanisms; Journal of the American Chemical Society; Vol. 136; No. 32; 11272-11275; PMCID PMC4140452; 10.1021/ja5059923
• Kanady, Jacob S. and Lin, Po-Heng, et el. (2014) Synthetic strategies towards a Mn4CaOn model complex of the oxygen-evolving complex of photosystem II; Abstracts of Papers of the American Chemical Society; Vol. 248; 989-INOR
• Radlauer, Madalyn R. and Agapie, Theodor (2014) Bimetallic Zirconium Amine Bis(phenolate) Polymerization Catalysts: Enhanced Activity and Tacticity Control for Polyolefin Synthesis; Organometallics; Vol. 33; No. 13; 3247-3250; PMCID PMC4216186; 10.1021/om500608j
• Agapie, Theodor (2014) Synthesis and properties of heterometallic cluster models of biological and heterogeneous water oxidation catalysts; Abstracts of Papers of the American Chemical Society; Vol. 247; 519-INOR
• Horak, Kyle T. and Velian, Alexandra, et el. (2014) Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine; Chemical Communications; Vol. 50; No. 34; 4427-4429; 10.1039/C4CC00838C
• Martin-Diaconescu, V. and Serena, D., et el. (2014) Application of X-ray Absorption (XAS) and Emission (XES) Spectroscopies to the Calcium Centers of PSII Oxygen Evolving Complex Structural Analogs; Journal of Biological Inorganic Chemistry; Vol. 19; No. S1; S498; 10.1007/s00775-014-1095-8
• Herbert, David E. and Lionetti, Davide, et el. (2013) Heterometallic Triiron-Oxo/Hydroxo Clusters: Effect of Redox-Inactive Metals; Journal of the American Chemical Society; Vol. 135; No. 51; 19075-19078; PMCID PMC3953215; 10.1021/ja4104974
• Tsui, Emily Y. and Kanady, Jacob S., et el. (2013) Synthetic Cluster Models of Biological and Heterogeneous Manganese Catalysts for O_2 Evolution; Inorganic Chemistry; Vol. 52; No. 24; 13833-13848; PMCID PMC3917504; 10.1021/ic402236f
• Suseno, Sandy and Horak, Kyle T., et el. (2013) Trinuclear Nickel Complexes with Metal–Arene Interactions Supported by Tris- and Bis(phosphinoaryl)benzene Frameworks; Organometallics; Vol. 32; No. 23; 6883-6886; PMCID PMC3920585; 10.1021/om400976x
• Herbert, David E. and Lara, Nadia C., et el. (2013) Arene C-H Amination at Nickel in Terphenyl–Diphosphine Complexes with Labile Metal–Arene Interactions; Chemistry-A European Journal; Vol. 19; No. 48; 16453-16460; PMCID PMC3897266; 10.1002/chem.201302539
• Lin, Sibo and Herbert, David E., et el. (2013) Dipalladium(I) Terphenyl Diphosphine Complexes as Models for Two-Site Adsorption and Activation of Organic Molecules; Journal of the American Chemical Society; Vol. 135; No. 42; 15830-15840; PMCID PMC3851319; 10.1021/ja406696k
• Kanady, Jacob S. and Tran, Rosalie, et el. (2013) Role of oxido incorporation and ligand lability in expanding redox accessibility of structurally related Mn4 clusters; Chemical Science; Vol. 4; No. 10; 3986-3996; PMCID PMC3806640; 10.1039/C3SC51406D
• Kelley, Paul and Day, Michael W., et el. (2013) Hydrogen Evolution Catalyzed by Aluminum-Bridged Cobalt Diglyoximate Complexes; European Journal of Inorganic Chemistry; Vol. 2013; No. 22-23; 3840-3845; 10.1002/ejic.201300309
• Tsui, Emily Y. and Agapie, Theodor (2013) Reduction potentials of heterometallic manganese-oxido cubane complexes modulated by redox-inactive metals; Proceedings of the National Academy of Sciences of the United States of America; Vol. 110; No. 25; 10084-10088; PMCID PMC3690856; 10.1073/pnas.1302677110
• Suseno, Sandy and Agapie, Theodor (2013) Intramolecular Arene C−H to C−P Functionalization Mediated by Nickel(II) and Palladium(II); Organometallics; Vol. 32; No. 11; 3161-3164; PMCID PMC3811949; 10.1021/om400424a
• Tsui, Emily Y. and Tran, Rosalie, et el. (2013) Redox-inactive metals modulate the reduction potential in heterometallic manganese–oxido clusters; Nature Chemistry; Vol. 5; No. 4; 293-299; PMCID PMC3654670; 10.1038/NCHEM.1578
• Radlauer, Madalyn R. and Buckley, Aya K., et el. (2013) Bimetallic Coordination Insertion Polymerization of Unprotected Polar Monomers: Copolymerization of Amino Olefins and Ethylene by Dinickel Bisphenoxyiminato Catalysts; Journal of the American Chemical Society; Vol. 135; No. 10; 3784-3787; 10.1021/ja4004816
• Kanady, Jacob S. and Mendoza-Cortés, José L., et el. (2013) Oxygen Atom Transfer and Oxidative Water Incorporation in Cuboidal Mn_(3)MO_n Complexes Based on Synthetic, Isotopic Labeling, and Computational Studies; Journal of the American Chemical Society; Vol. 135; No. 3; 1073-1082; 10.1021/ja310022p
• Lionetti, Davide and Day, Michael W., et el. (2013) Metal-templated ligand architectures for trinuclear chemistry: tricopper complexes and their O_2 reactivity; Chemical Science; Vol. 4; No. 2; 785-790; PMCID PMC3607385; 10.1039/c2sc21758a
• Mindiola, Daniel J. and Arnold, John, et el. (2012) New talent: Americas; Dalton Transactions; Vol. 41; No. 26; 7781-7781; 10.1039/c2dt90087d
• Kelley, Paul and Radlauer, Madalyn R., et el. (2012) Metallomacrocycles as ligands: synthesis and characterisation of aluminium-bridged bisglyoximato complexes of palladium and iron; Dalton Transactions; Vol. 41; No. 26; 8086-8092; 10.1039/c2dt30285c
• Kelley, Paul and Lin, Sibo, et el. (2012) Nickel-Mediated Hydrogenolysis of C–O Bonds of Aryl Ethers: What Is the Source of the Hydrogen?; Journal of the American Chemical Society; Vol. 134; No. 12; 5480-5483; PMCID PMC3340012; 10.1021/ja300326t
• Radlauer, Madalyn R. and Day, Michael W., et el. (2012) Dinickel Bisphenoxyiminato Complexes for the Polymerization of Ethylene and α-Olefins; Organometallics; Vol. 31; No. 6; 2231-2243; PMCID PMC3375993; 10.1021/om2011694
• Tonks, Ian A. and Tofan, Daniel, et el. (2012) Zirconium and Titanium Propylene Polymerization Precatalysts Supported by a Fluxional C_2-Symmetric Bis(anilide)pyridine Ligand; Organometallics; Vol. 31; No. 5; 1965-1974; 10.1021/om201262h
• Radlauer, Madalyn R. and Day, Michael W., et el. (2012) Bimetallic Effects on Ethylene Polymerization in the Presence of Amines: Inhibition of the Deactivation by Lewis Bases; Journal of the American Chemical Society; Vol. 134; No. 3; 1478-1481; PMCID PMC3307529; 10.1021/ja210990t
• Whited, Charlotte A. and Warren, Jeffrey J., et el. (2012) Gating NO Release from Nitric Oxide Synthase; Journal of the American Chemical Society; Vol. 134; No. 1; 27-30; PMCID PMC3257399; 10.1021/ja2069533
• Chao, Steven T. and Lara, Nadia C., et el. (2011) Reversible Halide-Modulated Nickel–Nickel Bond Cleavage: Metal–Metal Bonds as Design Elements for Molecular Devices; Angewandte Chemie International Edition; Vol. 50; No. 33; 7529-7532; PMCID PMC3805114; 10.1002/anie.201102797
• Kanady, Jacob S. and Tsui, Emily Y., et el. (2011) A Synthetic Model of the Mn_3Ca Subsite of the Oxygen-Evolving Complex in Photosystem II; Science; Vol. 333; No. 6043; 733-736; 10.1126/science.1206036
• Agapie, Theodor (2011) Selective ethylene oligomerization: Recent advances in chromium catalysis and mechanistic investigations; Coordination Chemistry Reviews; Vol. 255; No. 7-8; 861-880; 10.1016/j.ccr.2010.11.035
• Lin, Sibo and Day, Michael W., et el. (2011) Nickel Hydrides Supported by a Non-Innocent Diphosphine Arene Pincer: Mechanistic Studies of Nickel−Arene H-Migration and Partial Arene Hydrogenation; Journal of the American Chemical Society; Vol. 133; No. 11; 3828-3831; PMCID PMC3060299; 10.1021/ja200368y
• Tsui, Emily Y. and Day, Michael W., et el. (2011) Trinucleating Copper: Synthesis and Magnetostructural Characterization of Complexes Supported by a Hexapyridyl 1,3,5-Triarylbenzene Ligand; Angewandte Chemie International Edition; Vol. 50; No. 7; 1668-1672; 10.1002/anie.201005232
• Lin, Sibo and Agapie, Theodor (2011) Cross-Coupling Chemistry at Mononuclear and Dinuclear Nickel Complexes; Synlett; Vol. 2011; No. 1; 1-5; 10.1055/s-0030-1259093
• Tsui, Emily Y. and Kanady, Jacob S., et el. (2011) Trinuclear first row transition metal complexes of a hexapyridyl, trialkoxy 1,3,5-triarylbenzene ligand; Chemical Communications; Vol. 47; No. 14; 4189-4191; 10.1039/c0cc05608a
• Velian, Alexandra and Lin, Sibo, et el. (2010) Synthesis and C−C Coupling Reactivity of a Dinuclear Ni^I−Ni^I Complex Supported by a Terphenyl Diphosphine; Journal of the American Chemical Society; Vol. 132; No. 18; 6296-6297; 10.1021/ja101699a
• Agapie, Theodor and Day, Michael W., et el. (2008) Synthesis and reactivity of tantalum complexes supported by bidentate X2 and tridentate LX2 ligands with two phenolates linked to pyridine, thiophene, furan, and benzene connectors: mechanistic studies of the formation of a tantalum benzylidene and insertion chemistry for tantalum-carbon bonds; Organometallics; Vol. 27; No. 23; 6123-6142; 10.1021/om8002653
• Agapie, Theodor and Henling, Lawrence M., et el. (2008) Zirconium and titanium complexes supported by tridentate LX2 ligands having two phenolates linked to furan, thiophene, and pyridine donors: precatalysts for propylene polymerization and oligomerization; Organometallics; Vol. 27; No. 23; 6245-6256; 10.1021/om800136y
• Agapie, Theodor and Labinger, Jay A., et el. (2007) Mechanistic Studies of Olefin and Alkyne Trimerization with Chromium Catalysts: Deuterium Labeling and Studies of Regiochemistry Using a Model Chromacyclopentane Complex; Journal of the American Chemical Society; Vol. 129; No. 46; 14281-14295; 10.1021/ja073493h
• Agapie, Theodor and Bercaw, John E. (2007) Cyclometalated Tantalum Diphenolate Pincer Complexes: Intramolecular C−H/M−CH_3σ-Bond Metathesis May Be Faster than O−H/M−CH_3 Protonolysis; Organometallics; Vol. 26; No. 12; 2957-2959; 10.1021/om700284c
• Marinescu, Smaranda C. and Agapie, Theodor, et el. (2007) Group 3 Dialkyl Complexes with Tetradentate (L, L, N, O; L = N, O, S) Monoanionic Ligands: Synthesis and Reactivity; Organometallics; Vol. 26; No. 5; 1178-1190; 10.1021/om0608612
• Agapie, Theodor and Day, Michael W., et el. (2006) A Chromium-Diphosphine System for Catalytic Ethylene Trimerization: Synthetic and Structural Studies of Chromium Complexes with a Nitrogen-Bridged Diphosphine Ligand with ortho-Methoxyaryl Substituents; Organometallics; Vol. 25; No. 11; 2733-2742; 10.1021/om050605+
• Agapie, Theodor and Schofer, Susan J., et el. (2004) Mechanistic Studies of the Ethylene Trimerization Reaction with Chromium−Diphosphine Catalysts: Experimental Evidence for a Mechanism Involving Metallacyclic Intermediates; Journal of the American Chemical Society; Vol. 126; No. 5; 1304-1305; 10.1021/ja038968t
• Agapie, Theodor and Diaconescu, Paula L., et el. (2002) Radical Scission of Symmetrical 1,4-Dicarbonyl Compounds:  C−C Bond Cleavage with Titanium(IV) Enolate Formation and Related Reactions; Organometallics; Vol. 21; No. 7; 1329-1340; 10.1021/om0107284
• Agapie, Theodor and Diaconescu, Paula L., et el. (2002) Methine (CH) Transfer via a Chlorine Atom Abstraction/Benzene-Elimination Strategy:  Molybdenum Methylidyne Synthesis and Elaboration to a Phosphaisocyanide Complex; Journal of the American Chemical Society; Vol. 124; No. 11; 2412-2413; 10.1021/ja017278r
• Diaconescu, Paula L. and Odom, Aaron L., et el. (2001) Uranium−Group 14 Element Single Bonds: Isolation and Characterization of a Uranium(IV) Silyl Species; Organometallics; Vol. 20; No. 24; 4993-4995; 10.1021/om010575k
• Agapie, Theodor and Odom, Aaron L., et el. (2000) In Pursuit of the Molybdenum(III) Tris(thiolate) Fragment:  Unusual Structure of a Dimolybdenum μ-Nitrido Complex; Inorganic Chemistry; Vol. 39; No. 2; 174-179; 10.1021/ic9904891