[
    {
        "id": "authors:5dqs1-2a635",
        "collection": "authors",
        "collection_id": "5dqs1-2a635",
        "cite_using_url": "https://resolver.caltech.edu/CaltechAUTHORS:20140917-091954518",
        "type": "article",
        "title": "Electrochemical surface science twenty years later: Expeditions into the electrocatalysis of reactions at the core of artificial photosynthesis",
        "author": [
            {
                "family_name": "Soriaga",
                "given_name": "Manuel P.",
                "orcid": "0000-0002-0077-6226",
                "clpid": "Soriaga-Manuel-P"
            },
            {
                "family_name": "Baricuatro",
                "given_name": "Jack H.",
                "clpid": "Baricuatro-Jack-H"
            },
            {
                "family_name": "Cummins",
                "given_name": "Kyle D.",
                "clpid": "Cummins-Kyle-D"
            },
            {
                "family_name": "Kim",
                "given_name": "Youn-Geun",
                "orcid": "0000-0002-5936-6520",
                "clpid": "Kim-Youn-Geun"
            },
            {
                "family_name": "Saadi",
                "given_name": "Fadl H.",
                "orcid": "0000-0003-3941-0464",
                "clpid": "Saadi-Fadl-H"
            },
            {
                "family_name": "Sun",
                "given_name": "Guofeng",
                "clpid": "Sun-Guofeng"
            },
            {
                "family_name": "McCrory",
                "given_name": "Charles C. L.",
                "orcid": "0000-0001-9039-7192",
                "clpid": "McCrory-Charles-C-L"
            },
            {
                "family_name": "McKone",
                "given_name": "James R.",
                "orcid": "0000-0001-6445-7884",
                "clpid": "McKone-James-R"
            },
            {
                "family_name": "Velazquez",
                "given_name": "Jesus M.",
                "clpid": "Velazquez-Jesus-M"
            },
            {
                "family_name": "Ferrer",
                "given_name": "Ivonne M.",
                "clpid": "Ferrer-Ivonne-M"
            },
            {
                "family_name": "Carim",
                "given_name": "Azhar I.",
                "orcid": "0000-0003-3630-6872",
                "clpid": "Carim-Azhar-I"
            },
            {
                "family_name": "Javier",
                "given_name": "Alnald",
                "orcid": "0000-0002-0306-5462",
                "clpid": "Javier-Alnald-C"
            },
            {
                "family_name": "Chmielowiec",
                "given_name": "Brian",
                "orcid": "0000-0002-3004-9345",
                "clpid": "Chmielowiec-Brian"
            },
            {
                "family_name": "Lacy",
                "given_name": "David C.",
                "clpid": "Lacy-David-C"
            },
            {
                "family_name": "Gregoire",
                "given_name": "John M.",
                "orcid": "0000-0002-2863-5265",
                "clpid": "Gregoire-J-M"
            },
            {
                "family_name": "Sanabria-Chinchilla",
                "given_name": "Jean",
                "clpid": "Sanabria-Chinchilla-Jean"
            },
            {
                "family_name": "Amashukeli",
                "given_name": "Xenia",
                "clpid": "Amashukeli-Xenia"
            },
            {
                "family_name": "Royea",
                "given_name": "William J.",
                "clpid": "Royea-William-J"
            },
            {
                "family_name": "Brunschwig",
                "given_name": "Bruce S.",
                "orcid": "0000-0002-6135-6727",
                "clpid": "Brunschwig-Bruce-S"
            },
            {
                "family_name": "Hemminger",
                "given_name": "John C.",
                "clpid": "Hemminger-John-C"
            },
            {
                "family_name": "Lewis",
                "given_name": "Nathan S.",
                "orcid": "0000-0001-5245-0538",
                "clpid": "Lewis-N-S"
            },
            {
                "family_name": "Stickney",
                "given_name": "John L.",
                "clpid": "Stickney-John-L"
            }
        ],
        "abstract": "Surface science research fixated on phenomena and processes that transpire at the electrode-electrolyte interface has been pursued in the past. A considerable proportion of the earlier work was on materials and reactions pertinent to the operation of small-molecule fuel cells. The experimental approach integrated a handful of surface-sensitive physical\u2013analytical methods with traditional electrochemical techniques, all harbored in a single environment-controlled electrochemistry-surface science apparatus (EC-SSA); the catalyst samples were typically precious noble metals constituted of well-defined single-crystal surfaces. More recently, attention has been diverted from fuel-to-energy generation to its converse, (solar) energy-to-fuel transformation; e.g., instead of water synthesis (from hydrogen and oxygen) in fuel cells, water decomposition (to hydrogen and oxygen) in artificial photosynthesis. The rigorous surface-science protocols remain unchanged but the experimental capabilities have been expanded by the addition of several characterization techniques, either as EC-SSA components or as stand-alone instruments. The present manuscript describes results selected from on-going studies of earth-abundant electrocatalysts for the reactions that underpin artificial photosynthesis: nickel-molybdenum alloys for the hydrogen evolution reaction, calcium birnessite as a heterogeneous analogue for the oxygen-evolving complex in natural photosynthesis, and single-crystalline copper in relation to the carbon dioxide reduction reaction.",
        "doi": "10.1016/j.susc.2014.06.028",
        "issn": "0039-6028",
        "publisher": "Elsevier",
        "publication": "Surface Science",
        "publication_date": "2015-01",
        "volume": "631",
        "pages": "285-294"
    }
]