Bercaw, John

Combined from CaltechAUTHORS

• Bercaw, John and Berke, Heinz, et el. (2019) Hans Herbert Brintzinger (1935–2019); Angewandte Chemie International Edition; Vol. 58; No. 34; 11569; 10.1002/anie.201907530
• Panchenko, Valentina N. and Babushkin, Dmitrii E., et el. (2019) Catalyst Speciation During ansa-Zirconocene-Catalyzed Polymerization of 1-Hexene Studied by UV-vis Spectroscopy—Formation and Partial Re-Activation of Zr-Allyl Intermediates; Polymers; Vol. 11; No. 6; Art. No. 936; PMCID PMC6630943; 10.3390/polym11060936
• Bercaw, John E. and Labinger, Jay A. (2019) Malcolm L. H. Green: Reminiscences and Appreciations; Inorganica Chimica Acta; Vol. 487; 405-408; 10.1016/j.ica.2018.12.044
• Bercaw, John (2018) Mechanistic studies inspired by Jack
• Bercaw, John E. (2018) Jack Halpern (1925–2018): Pioneer of homogeneous catalysis; Proceedings of the National Academy of Sciences of the United States of America; Vol. 115; No. 20; 5049-5050; PMCID PMC5960341; 10.1073/pnas.1806116115
• Bercaw, John E. (2018) Olefin trimerization and ethylene tandem conversion to linear low density polyethylene
• Steelman, D. Keith and Aluthge, Dinesh C., et el. (2017) Mechanistic Studies on Selective Trimerization of Linear α-Olefins over a Supported Titanium Catalyst; ACS Catalysis; Vol. 7; No. 8; 4922-4926; 10.1021/acscatal.7b00256
• Bercaw, John E. (2017) Award Address (Gabor A. Somorjai Award for Creative Research in Catalysis sponsored by the Gabor A. & Judith K. Somorjai Endowment Fund). Mechanistic studies of 1-alkene trimerization and polymerization with organotransition metal catalysts
• Bercaw, John E. and Aluthge, Dinesh, et el. (2017) Olefin trimerization with titanium catalysts: MAO/silica-supported variants display higher productivities
• Aluthge, Dinesh and Sattler, Aaron, et el. (2017) Co-supported tandem catalysts for production of linear low density polyethylene
• Aluthge, Dinesh C. and Sattler, Aaron, et el. (2016) Cosupported Tandem Catalysts for Production of Linear Low-Density Polyethylene from an Ethylene-Only Feed; ACS Catalysis; Vol. 6; No. 10; 6581-6584; 10.1021/acscatal.6b02370
• Bercaw, John E. and Labinger, Jay A., et el. (2016) Homogeneous Ta/Ir tandem catalytic alkane/alkene coupling
• Bercaw, John and Do, Loi, et el. (2016) Ethylene and alpha olefin trimerization and tandem trimerization/polymerization of ethylene
• Labinger, Jay and Bercaw, John, et el. (2016) Oligo or poly? A mechanistic interpretation of a switchable catalyst
• Sattler, Aaron and Aluthge, Dinesh C., et el. (2016) Enhanced Productivity of a Supported Olefin Trimerization Catalyst; ACS Catalysis; Vol. 6; No. 1; 19-22; 10.1021/acscatal.5b02604
• Despagnet-Ayoub, Emmanuelle and Takase, Michael K., et el. (2015) Mechanistic Insights on the Controlled Switch from Oligomerization to Polymerization of 1-Hexene Catalyzed by an NHC-Zirconium Complex; Organometallics; Vol. 34; No. 19; 4707-4716; 10.1021/acs.organomet.5b00472
• Mindiola, Daniel J. and Smith, Milton R., et el. (2015) Gregory L. Hillhouse: His Life, His Art, His Science, and the Rise of "Double Nickel"; Organometallics; Vol. 34; No. 19; 4633-4636; 10.1021/acs.organomet.5b00527
• Labinger, Jay A. and Bercaw, John E. (2015) Mechanistic studies on the Shilov system: A retrospective; Journal of Organometallic Chemistry; Vol. 793; 47-53; 10.1016/j.jorganchem.2015.01.027
• Despagnet-Ayoub, Emmanuelle and Takase, Michael K., et el. (2015) Reversible 1,2-Alkyl Migration to Carbene and Ammonia Activation in an N-Heterocyclic Carbene–Zirconium Complex; Journal of the American Chemical Society; Vol. 137; No. 33; 10500-10503; 10.1021/jacs.5b06695
• Bercaw, John E. and Labinger, Jay A., et el. (2015) Linear low density polyethylenes using well defined tandem catalysts and a single monomer feed
• Bercaw, John E. and Leitch, David C., et el. (2015) Tandem catalytic processes for light alkane upgrading and ethylene polymerization
• Labinger, Jay A. and Leitch, David C., et el. (2015) Upgrading Light Hydrocarbons: A Tandem Catalytic System for Alkane/Alkene Coupling; Topics in Catalysis; Vol. 58; No. 7-9; 494-501; 10.1007/s11244-015-0380-2
• Winston, Matthew S. and Bercaw, John E. (2014) Palladium(II) Complexes Supported by a Bidentate Bis(secondary)phosphine Linked by Pyridine; Inorganica Chimica Acta; Vol. 422; 30-35; 10.1016/j.ica.2014.08.002
• Teets, Thomas S. and Labinger, Jay A., et el. (2014) Guanidine-Functionalized Rhenium Cyclopentadienyl Carbonyl Complexes: Synthesis and Cooperative Activation of H–H and O–H Bonds; Organometallics; Vol. 33; No. 15; 4107-4117; 10.1021/om500650b
• Despagnet-Ayoub, Emmanuelle and Labinger, Jay A., et el. (2014) N-Heterocyclic carbene group 4 transition metal catalysts: Synthesis and reactivity towards oligomerization/polymerization of α-olefins; Abstracts of Papers of the American Chemical Society; Vol. 248; 527-INOR
• Sattler, Aaron and Winkler, Jay R., et el. (2014) Upgrading light olefins by trimerization catalysis
• Sattler, Aaron and VanderVelde, David G., et el. (2014) Lewis Acid Promoted Titanium Alkylidene Formation: Off-Cycle Intermediates Relevant to Olefin Trimerization Catalysis; Journal of the American Chemical Society; Vol. 136; No. 30; 10790-10800; 10.1021/ja5055687
• Leitch, David C. and Labinger, Jay A., et el. (2014) Scope and Mechanism of Homogeneous Tantalum/Iridium Tandem Catalytic Alkane/Alkene Upgrading using Sacrificial Hydrogen Acceptors; Organometallics; Vol. 33; No. 13; 3353-3365; 10.1021/om500231t
• Klet, Rachel C. and Theriault, Curt N., et el. (2014) Investigations into Asymmetric Post-Metallocene Group 4 Complexes for the Synthesis of Highly Regioirregular Polypropylene; Macromolecules; Vol. 47; No. 10; 3317-3324; 10.1021/ma500453t
• Min, Endy Y.-J. and Bercaw, John E., et el. (2014) Bis(η^5-Pentamethylcyclopentadienyl) Complexes of Titanium, Zirconium, and Hafnium; ISBN 9781118744871; Inorganic Syntheses; 47-51; 10.1002/9781118744994.ch10
• Min, Endy Y.-J and Bercaw, John E., et el. (2014) Bis(η⁵-Pentamethylcyclopentadienyl) Complexes of Scandium; ISBN 9781118744871; Inorganic Syntheses; 42-47; 10.1002/9781118744994.ch09
• Shin, Jun Ho and Churchill, David G., et el. (2014) Bis(η⁵-Pentamethylcyclopentadienyl) Complexes of Molybdenum; ISBN 9781118744871; Inorganic Syntheses; 58-62; 10.1002/9781118744994.ch12
• Min, Endy Y.-J and Bercaw, John E., et el. (2014) Bis(η^5-Pentamethylcyclopentadienyl) Complexes of Niobium and Tantalum; ISBN 9781118744871; Inorganic Syntheses; 52-57; 10.1002/9781118744994.ch11
• Labinger, Jay A. and Leitch, David C., et el. (2014) Upgrading light hydrocarbons: A tandem catalytic system for alkane/alkene coupling
• Sattler, Aaron and Labinger, Jay A., et el. (2013) Highly Selective Olefin Trimerization Catalysis by a Borane-Activated Titanium Trimethyl Complex; Organometallics; Vol. 32; No. 23; 6899-6902; 10.1021/om401098m
• Do, Loi H. and Labinger, Jay A., et el. (2013) Spectral Studies of a Cr(PNP)−MAO System for Selective Ethylene Trimerization Catalysis: Searching for the Active Species; ACS Catalysis; Vol. 3; No. 11; 2582-2585; PMCID PMC3855459; 10.1021/cs400778a
• Teets, Thomas S. and Labinger, Jay A., et el. (2013) A Thermodynamic Analysis of Rhenium(I)−Formyl C−H Bond Formation via Base-Assisted Heterolytic H_2 Cleavage in the Secondary Coordination Sphere; Organometallics; Vol. 32; No. 19; 5530-5545; 10.1021/om400810v
• Despagnet-Ayoub, Emmanuelle and Henling, Lawrence M., et el. (2013) Addition of a phosphine ligand switches an N-heterocyclic carbene-zirconium catalyst from oligomerization to polymerization of 1-hexene; Dalton Transactions; Vol. 42; No. 44; 15544-15547; 10.1039/C3DT52342J
• Kamal, Muhammad Shahzad and Bahuleyan, Bijal Kottukkal, et el. (2013) Crystallization analysis fractionation of poly(ethylene-co-styrene) produced by metallocene catalysts; Polymer Bulletin; Vol. 70; No. 9; 2645-2656; 10.1007/s00289-013-0980-6
• Appel, Aaron M. and Bercaw, John E., et el. (2013) Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO_2 Fixation; Chemical Reviews; Vol. 113; No. 8; 6621-6658; PMCID PMC3895110; 10.1021/cr300463y
• Lenton, Taylor N. and Bercaw, John E., et el. (2013) Formation of Trivalent Zirconocene Complexes from ansa-Zirconocene-Based Olefin-Polymerization Precatalysts: An EPR- and NMR-Spectroscopic Study; Journal of the American Chemical Society; Vol. 135; No. 29; 10710-10719; 10.1021/ja403170u
• Leitch, David C. and Lam, Yan Choi, et el. (2013) Upgrading Light Hydrocarbons via Tandem Catalysis: A Dual Homogeneous Ta/Ir System for Alkane/Alkene Coupling; Journal of the American Chemical Society; Vol. 135; No. 28; 10302-10305; 10.1021/ja405191a
• Tonks, Ian A. and Meier, Josef C., et el. (2013) Alkyne Hydroamination and Trimerization with Titanium Bis(phenolate)pyridine Complexes: Evidence for Low-Valent Titanium Intermediates and Synthesis of an Ethylene Adduct of Titanium(II); Organometallics; Vol. 32; No. 12; 3451-3457; 10.1021/om400080g
• Ahmed, Tonia S. and Tonks, Ian A., et el. (2013) Kinetics and Mechanism of Indene C–H Bond Activation by [(COD)Ir(μ_2-OH)]_2; Organometallics; Vol. 32; No. 11; 3322-3326; 10.1021/om400230j
• Despagnet-Ayoub, Emmanuelle and Henling, Lawrence M., et el. (2013) Group 4 Transition-Metal Complexes of an Aniline–Carbene–Phenol Ligand; Organometallics; Vol. 32; No. 10; 2934-2938; 10.1021/om4001567
• Bercaw, John E. and Labinger, Jay A., et el. (2013) Reductive coupling of carbon monoxide in carbonyl complexes with pendant Lewis acids or bases
• Bercaw, John E. and Labinger, Jay A., et el. (2013) New precatalysts for olefin polymerization having LX2 pincer ligands
• Despagnet-Ayoub, Emmanuelle and Miqueu, Karinne, et el. (2013) Unexpected rearrangements in the synthesis of an unsymmetrical tridentate dianionic N-heterocyclic carbene; Chemical Science; Vol. 4; No. 5; 2117-2121; 10.1039/c3sc22171g
• Lenton, Taylor N. and VanderVelde, David G., et el. (2012) Synthesis of a Bis(thiophenolate)pyridine Ligand and Its Titanium, Zirconium, and Tantalum Complexes; Organometallics; Vol. 31; No. 21; 7492-7499; 10.1021/om300789h
• Winston, Matthew S. and Oblad, Paul F., et el. (2012) Activator-Free Olefin Oligomerization and Isomerization Reactions Catalyzed by an Air- and Water-Tolerant Wacker Oxidation Intermediate; Angewandte Chemie International Edition; Vol. 51; No. 39; 9822-9824; 10.1002/anie.201206215
• Klet, Rachel C. and Labinger, Jay A., et el. (2012) Diverse C−C Bond-Forming Reactions of Bis(carbene)platinum(II) Complexes; Organometallics; Vol. 31; No. 18; 6652-6657; 10.1021/om300733h
• Hazari, Amaruka and Labinger, Jay A., et el. (2012) A Versatile Ligand Platform that Supports Lewis Acid Promoted Migratory Insertion; Angewandte Chemie International Edition; Vol. 51; No. 33; 8268-8271; 10.1002/anie.201203264
• Do, Loi H. and Labinger, Jay A., et el. (2012) Mechanistic Studies of Ethylene and α-Olefin Co-Oligomerization Catalyzed by Chromium−PNP Complexes; Organometallics; Vol. 31; No. 14; 5143-5149; 10.1021/om300492r
• Klet, Rachel C. and VanderVelde, David G., et el. (2012) Highly regioirregular polypropylene from asymmetric group 4 anilide(pyridine)phenoxide complexes; Chemical Communications; Vol. 48; No. 53; 6657-6659; 10.1039/C2CC32806B
• Atiqullah, M. and Winston, M. S., et el. (2012) Effects of a vanadium post-metallocene catalyst-induced polymer backbone inhomogeneity on UV oxidative degradation of the resulting polyethylene film; Polymer Degradation and Stability; Vol. 97; No. 7; 1164-1177; 10.1016/j.polymdegradstab.2012.03.042
• Tonks, Ian A. and Durrell, Alec C., et el. (2012) Groups 5 and 6 Terminal Hydrazido(2−) Complexes: N_β Substituent Effects on Ligand-to-Metal Charge-Transfer Energies and Oxidation States; Journal of the American Chemical Society; Vol. 134; No. 17; 7301-7304; 10.1021/ja302275j
• Tonks, Ian A. and Tofan, Daniel, et el. (2012) Zirconium and Titanium Propylene Polymerization Precatalysts Supported by a Fluxional C_2-Symmetric Bis(anilide)pyridine Ligand; Organometallics; Vol. 31; No. 5; 1965-1974; 10.1021/om201262h
• Fu, Ross and Bercaw, John E., et el. (2011) Intra- and Intermolecular C−H Activation by Bis(phenolate)pyridineiridium(III) Complexes; Organometallics; Vol. 30; No. 24; 6751-6765; 10.1021/om201069k
• Miller, Alexander J. M. and Labinger, Jay A., et el. (2011) Trialkylborane-Assisted CO_2 Reduction by Late Transition Metal Hydrides; Organometallics; Vol. 30; No. 16; 4308-4314; 10.1021/om200364w
• Scott, Valerie J. and Labinger, Jay A., et el. (2011) Large Kinetic Isotope Effects for the Protonolysis of Metal-Methyl Complexes Are Not Reliable Mechanistic Indicators; Organometallics; Vol. 30; No. 16; 4374-4378; 10.1021/om200432b
• West, Nathan M. and Labinger, Jay A., et el. (2011) Heterobimetallic Complexes of Rhenium and Zinc: Potential Catalysts for Homogeneous Syngas Conversion; Organometallics; Vol. 30; No. 10; 2690-2700; 10.1021/om200051u
• West, Nathan M. and Miller, Alexander J. M., et el. (2011) Homogeneous syngas conversion; Coordination Chemistry Reviews; Vol. 255; No. 7-8; 881-898; 10.1016/j.ccr.2010.08.019
• Baldwin, Steven M. and Bercaw, John E., et el. (2011) Cationic Alkylaluminum-Complexed Zirconocene Hydrides: NMR-Spectroscopic Identification, Crystallographic Structure Determination, and Interconversion with Other Zirconocene Cations; Journal of the American Chemical Society; Vol. 133; No. 6; 1805-1813; 10.1021/ja1050428
• Labinger, Jay A. and Bercaw, John E. (2011) The Role of Higher Oxidation State Species in Platinum-Mediated C–H Bond Activation and Functionalization; ISBN 978-3-642-17428-5; Higher Oxidation State Organopalladium and Platinum Chemistry; 29-59; 10.1007/978-3-642-17429-2_2
• Winston, Matthew S. and Bercaw, John E. (2010) A Novel Bis(phosphido)pyridine [PNP]^(2−) Pincer Ligand and Its Potassium and Bis(dimethylamido)zirconium(IV) Complexes; Organometallics; Vol. 29; No. 23; 6408-6416; 10.1021/om100775g
• Golisz, Suzanne R. and Labinger, Jay A., et el. (2010) Intramolecular C−H Activation of a Bisphenolate(benzene)-Ligated Titanium Dibenzyl Complex. Competing Pathways Involving α-Hydrogen Abstraction and σ-Bond Metathesis; Organometallics; Vol. 29; No. 21; 5026-5032; 10.1021/om100253u
• Miller, Alexander J. M. and Labinger, Jay A., et el. (2010) Homogeneous CO Hydrogenation: Ligand Effects on the Lewis Acid-Assisted Reductive Coupling of Carbon Monoxide; Organometallics; Vol. 29; No. 20; 4499-4516; 10.1021/om100638d
• Baldwin, Steven M. and Bercaw, John E., et el. (2010) Cationic Alkylaluminum-Complexed Zirconocene Hydrides as Participants in Olefin Polymerization Catalysis; Journal of the American Chemical Society; Vol. 132; No. 40; 13969-13971; 10.1021/ja105040r
• Bercaw, John E. and Chen, George S., et el. (2010) Protonolysis of Platinum(II) and Palladium(II) Methyl Complexes: A Combined Experimental and Theoretical Investigation; Organometallics; Vol. 29; No. 19; 4354-4359; 10.1021/om100655w
• Scott, Valerie J. and Labinger, Jay A., et el. (2010) Mechanism of Reductive Elimination of Methyl Iodide from a Novel Gold(III)−Monomethyl Complex; Organometallics; Vol. 29; No. 18; 4090-4096; 10.1021/om1006566
• Tonks, Ian A. and Bercaw, John E. (2010) (dme)MCl_3(NNPh_2) (dme= dimethoxyethane; M= Nb, Ta): A Versatile Synthon for [Ta═NNPh_2] Hydrazido(2-) Complexes; Inorganic Chemistry; Vol. 49; No. 10; 4648-4656; 10.1021/ic1004193
• Fulmer, Gregory R. and Miller, Alexander J. M., et el. (2010) NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist; Organometallics; Vol. 29; No. 9; 2176-2179; 10.1021/om100106e
• Wilson, Aaron D. and Miller, Alexander J. M., et el. (2010) Thermodynamic Studies of [H_(2)Rh(diphosphine)2]^+ and [HRh(diphosphine)(2)(CH_(3)CN)]^(2+) Complexes in Acetonitrile; Inorganic Chemistry; Vol. 49; No. 8; 3918-3926; 10.1021/ic100117y
• Miller, Alexander J. M. and Labinger, Jay A., et el. (2010) Homogeneous CO Hydrogenation: Dihydrogen Activation Involves a Frustrated Lewis Pair Instead of a Platinum Complex; Journal of the American Chemical Society; Vol. 132; No. 10; 3301-3303; 10.1021/ja100574n
• Oblad, Paul F. and Bercaw, John E., et el. (2010) Oxidation of Organometallic Platinum and Palladium Complexes Obtained from C−H Activation; Organometallics; Vol. 29; No. 4; 789-794; 10.1021/om900678z
• Bercaw, John E. and Durrell, Alec C., et el. (2010) Electronic Structures of Pd^(II) Dimers; Inorganic Chemistry; Vol. 49; No. 4; 1801-1810; 10.1021/ic902189g
• Weinberg, David R. and Hazari, Nilay, et el. (2010) Iridium(I) and Iridium(III) Complexes Supported by a Diphenolate Imidazolyl-Carbene Ligand; Organometallics; Vol. 29; No. 1; 89-100; 10.1021/om900803r
• Miller, Alexander J. M. and Bercaw, John E. (2010) Dehydrogenation of amine–boranes with a frustrated Lewis pair; Chemical Communications; Vol. 46; No. 10; 1709-1711; 10.1039/b925659h
• Golisz, Suzanne R. and Bercaw, John E. (2009) Synthesis of Early Transition Metal Bisphenolate Complexes and Their Use as Olefin Polymerization Catalysts; Macromolecules; Vol. 42; No. 22; 8751-8762; 10.1021/ma901659q
• Golisz, Suzanne R. and Hazari, Nilay, et el. (2009) Activation of the C−N Bond in Nitromethane by Palladium α-Diimine Complexes; Journal of Organic Chemistry; Vol. 74; No. 21; 8441-8443; 10.1021/jo901635g
• Elowe, Paul R. and West, Nathan M., et el. (2009) Transformations of Group 7 Carbonyl Complexes: Possible Intermediates in a Homogeneous Syngas Conversion Scheme; Organometallics; Vol. 28; No. 21; 6218-6227; 10.1021/om900804j
• Bercaw, John E. and Hazari, Nilay, et el. (2009) Activation of a C−H Bond in Indene by [(COD)Rh(μ_2-OH)]_2; Organometallics; Vol. 28; No. 18; 5489-5492; 10.1021/om9004498
• Chen, George S. and Labinger, Jay A., et el. (2009) Selective Oxidation of sp^3 C-H Bonds in Water Catalyzed by a Glycinate-Platinum(II) Complex; Organometallics; Vol. 28; No. 17; 4899-4901; 10.1021/om900267w
• Bercaw, John E. and Day, Michael W., et el. (2009) Robotic Lepidoptery: Structural Characterization of (mostly) Unexpected Palladium Complexes Obtained from High-Throughput Catalyst Screening; Organometallics; Vol. 28; No. 17; 5017-5024; 10.1021/om900240a
• Lin, Bo-Lin and Bhattacharyya, Koyel X., et el. (2009) Competitive Benzene C−H Bond Activation versus Olefin Insertion in a (Monomethyl)palladium(II) β-Diketiminate Complex; Organometallics; Vol. 28; No. 15; 4400-4405; 10.1021/om900171d
• Scott, Valerie J. and Henling, Lawrence M., et el. (2009) Competitive Activation of a Methyl C−H Bond of Dimethylformamide at an Iridium Center; Organometallics; Vol. 28; No. 14; 4229-4230; 10.1021/om9002413
• Tonks, Ian A. and Henling, Larry M., et el. (2009) Amine, Amido, and Imido Complexes of Tantalum Supported by a Pyridine-Linked Bis(phenolate) Pincer Ligand: Ta−N π-Bonding Influences Pincer Ligand Geometry; Inorganic Chemistry; Vol. 48; No. 12; 5096-5105; 10.1021/ic802234x
• Weintrob, Edward C. and Tofan, Daniel, et el. (2009) Synthesis and Characterization of Iron Derivatives Having a Pyridine-Linked Bis(anilide) Pincer Ligand; Inorganic Chemistry; Vol. 48; No. 8; 3808-3813; 10.1021/ic900083s
• Lin, Bo-Lin and Labinger, Jay A., et el. (2009) Mechanistic investigations of bipyrimidine-promoted palladium-catalyzed allylic acetoxylation of olefins; Canadian Journal of Chemistry; Vol. 87; No. 1; 264-271; 10.1139/V08-133
• Agapie, Theodor and Day, Michael W., et el. (2008) Synthesis and reactivity of tantalum complexes supported by bidentate X2 and tridentate LX2 ligands with two phenolates linked to pyridine, thiophene, furan, and benzene connectors: mechanistic studies of the formation of a tantalum benzylidene and insertion chemistry for tantalum-carbon bonds; Organometallics; Vol. 27; No. 23; 6123-6142; 10.1021/om8002653
• Agapie, Theodor and Henling, Lawrence M., et el. (2008) Zirconium and titanium complexes supported by tridentate LX2 ligands having two phenolates linked to furan, thiophene, and pyridine donors: precatalysts for propylene polymerization and oligomerization; Organometallics; Vol. 27; No. 23; 6245-6256; 10.1021/om800136y
• Bercaw, John E. and Hazari, Nilay, et el. (2008) C-H Bond Activation by [{(Diimine)Pd(μ-OH)}2]2+ Dimers: Mechanism-Guided Catalytic Improvement; Angewandte Chemie International Edition; Vol. 47; No. 51; 9941-9943; 10.1002/anie.200804455
• Bercaw, John E. and Chen, George S., et el. (2008) Hydrogen tunneling in protonolysis of platinum(II) and palladium(II) methyl complexes: mechanistic implications; Journal of the American Chemical Society; Vol. 130; No. 52; 17654-17655; 10.1021/ja807427d
• Baldwin, Steven M. and Bercaw, John E., et el. (2008) Alkylaluminum-complexed zirconocene hydrides: identification of hydride-bridged species by NMR spectroscopy; Journal of the American Chemical Society; Vol. 130; No. 51; 17423-17433; 10.1021/ja8054723
• Bercaw, John E. and Hazari, Nilay, et el. (2008) Oxidative aromatization of olefins with dioxygen catalyzed by palladium trifluoroacetate; Journal of Organic Chemistry; Vol. 73; No. 21; 8654-8657; 10.1021/jo8016296
• Miller, Alexander J. M. and Labinger, Jay A., et el. (2008) Reductive Coupling of Carbon Monoxide in a Rhenium Carbonyl Complex with Pendant Lewis Acids; Journal of the American Chemical Society; Vol. 130; No. 36; 11874-11875; 10.1021/ja805108z
• Bercaw, John E. and Hazari, Nilay, et el. (2008) Selective Methylative Homologation: An Alternate Route to Alkane Upgrading; Journal of the American Chemical Society; Vol. 130; No. 36; 11988-11995; 10.1021/ja803029s
• Min, Endy Y.-J. and Byers, Jeffery A., et el. (2008) Catalyst Site Epimerization during the Kinetic Resolution of Chiral α-Olefins by Polymerization; Organometallics; Vol. 27; No. 10; 2179-2188; 10.1021/om700778e
• Williams, Travis J. and Caffyn, Andrew J. M., et el. (2008) C−H Bond Activation by Air-Stable [(Diimine)M^(II)(μ_2-OH)]_2^(2+)Dimers (M = Pd, Pt); Journal of the American Chemical Society; Vol. 130; No. 8; 2418-2419; 10.1021/ja076740q
• Bercaw, John E. and Diaconescu, Paula L., et el. (2007) Conversion of Methanol to 2,2,3-Trimethylbutane (Triptane) over Indium(III) Iodide; Inorganic Chemistry; Vol. 46; No. 26; 11371-11380; 10.1021/ic7014447
• Agapie, Theodor and Labinger, Jay A., et el. (2007) Mechanistic Studies of Olefin and Alkyne Trimerization with Chromium Catalysts: Deuterium Labeling and Studies of Regiochemistry Using a Model Chromacyclopentane Complex; Journal of the American Chemical Society; Vol. 129; No. 46; 14281-14295; 10.1021/ja073493h
• Bercaw, John E. and Grubbs, Robert H., et el. (2007) Enhanced selectivity in the conversion of methanol to 2,2,3-trimethylbutane (triptane) over zinc iodide by added phosphorous or hypophosphorous acid; Chemical Communications; Vol. 2007; No. 28; 2974-2976; 10.1039/b705470j
• Agapie, Theodor and Bercaw, John E. (2007) Cyclometalated Tantalum Diphenolate Pincer Complexes: Intramolecular C−H/M−CH_3σ-Bond Metathesis May Be Faster than O−H/M−CH_3 Protonolysis; Organometallics; Vol. 26; No. 12; 2957-2959; 10.1021/om700284c
• Klamo, Sara B. and Wendt, Ola F., et el. (2007) Dialkyl and Methyl-Alkyl Zirconocenes: Synthesis and Characterization of Zirconocene-Alkyls That Model the Polymeryl Chain in Alkene Polymerizations; Organometallics; Vol. 26; No. 12; 3018-3030; 10.1021/om0601302
• Bercaw, John E. and Labinger, Jay A. (2007) The coordination chemistry of saturated molecules; Proceedings of the National Academy of Sciences of the United States of America; Vol. 104; No. 17; 6899-6900; PMCID PMC1855396; 10.1073/pnas.0700902104
• Chen, George S. and Labinger, Jay A., et el. (2007) The role of alkane coordination in C–H bond cleavage at a Pt(II) center; Proceedings of the National Academy of Sciences of the United States of America; Vol. 104; No. 17; 6915-6920; PMCID PMC1855376; 10.1073/pnas.0610981104
• Marinescu, Smaranda C. and Agapie, Theodor, et el. (2007) Group 3 Dialkyl Complexes with Tetradentate (L, L, N, O; L = N, O, S) Monoanionic Ligands: Synthesis and Reactivity; Organometallics; Vol. 26; No. 5; 1178-1190; 10.1021/om0608612
• Williams, Travis J. and Labinger, Jay A., et el. (2007) Reactions of Indene and Indoles with Platinum Methyl Cations: Indene C−H Activation, Indole π versus Nitrogen Lone-Pair Coordination; Organometallics; Vol. 26; No. 2; 281-287; PMCID PMC4833004; 10.1021/om0606643
• Driver, Tom G. and Williams, Travis J., et el. (2007) C−H Bond Activation by Dicationic Platinum(II) Complexes; Organometallics; Vol. 26; No. 2; 294-301; 10.1021/om060792r
• Weinberg, David R. and Labinger, Jay A., et el. (2007) Competitive Oxidation and Protonation of Aqueous Monomethylplatinum(II) Complexes: A Comparison of Oxidants; Organometallics; Vol. 26; No. 1; 167-172; 10.1021/om060763g
• Bercaw, John E. and Diaconescu, Paula L., et el. (2006) On the Mechanism of the Conversion of Methanol to 2,2,3-Trimethylbutane (Triptane) over Zinc Iodide; Journal of Organic Chemistry; Vol. 71; No. 23; 8907-8917; 10.1021/jo0617823
• Elowe, Paul R. and McCann, Cassandra, et el. (2006) Nitrogen-Linked Diphosphine Ligands with Ethers Attached to Nitrogen for Chromium-Catalyzed Ethylene Tri- and Tetramerizations; Organometallics; Vol. 25; No. 22; 5255-5260; 10.1021/om0601596
• Byers, Jeffery A. and Bercaw, John E. (2006) Kinetic resolution of racemic {alpha}-olefins with ansa-zirconocene polymerization catalysts: Enantiomorphic site vs. chain end control; Proceedings of the National Academy of Sciences of the United States of America; Vol. 103; No. 42; 15303-15308; PMCID PMC1622822; 10.1073/pnas.0603071103
• Miller, Stephen A. and Bercaw, John E. (2006) Mechanism of Isotactic Polypropylene Formation with C_1-Symmetric Metallocene Catalysts; Organometallics; Vol. 25; No. 15; 3576-3592; 10.1021/om050841k
• Schofer, Susan J. and Day, Michael W., et el. (2006) Ethylene Trimerization Catalysts Based on Chromium Complexes with a Nitrogen-Bridged Diphosphine Ligand Having ortho-Methoxyaryl or ortho-Thiomethoxy Substituents: Well-Defined Catalyst Precursors and Investigations of the Mechanism; Organometallics; Vol. 25; No. 11; 2743-2749; 10.1021/om0506062
• Agapie, Theodor and Day, Michael W., et el. (2006) A Chromium-Diphosphine System for Catalytic Ethylene Trimerization: Synthetic and Structural Studies of Chromium Complexes with a Nitrogen-Bridged Diphosphine Ligand with ortho-Methoxyaryl Substituents; Organometallics; Vol. 25; No. 11; 2733-2742; 10.1021/om050605+
• Owen, Jonathan S. and Labinger, Jay A., et el. (2006) Kinetics and Mechanism of Methane, Methanol, and Dimethyl Ether C−H Activation with Electrophilic Platinum Complexes; Journal of the American Chemical Society; Vol. 128; No. 6; 2005-2016; 10.1021/ja056387t
• Lersch, Martin and Dalhus, Bjørn, et el. (2006) Improved One-Pot Synthesis of Mixed Methyl−Aryl Platinum(II) Diimine Complexes; Organometallics; Vol. 25; No. 4; 1055-1058; 10.1021/om050899z
• Chirik, Paul J. and Bercaw, John E. (2005) Cyclopentadienyl and Olefin Substituent Effects on Insertion and β-Hydrogen Elimination with Group 4 Metallocenes. Kinetics, Mechanism, and Thermodynamics for Zirconocene and Hafnocene Alkyl Hydride Derivatives; Organometallics; Vol. 24; No. 22; 5407-5423; 10.1021/om0580351
• Driver, Tom G. and Day, Michael W., et el. (2005) Mechanism of C−H Bond Activation of Alkyl-Substituted Benzenes by Cationic Platinum(II) Complexes; Organometallics; Vol. 24; No. 15; 3644-3654; 10.1021/om050251m
• Chirik, Paul J. and Dalleska, Nathan F., et el. (2005) Experimental Evidence for γ-Agostic Assistance in β-Methyl Elimination, the Microscopic Reverse of α-Agostic Assistance in the Chain Propagation Step of Olefin Polymerization; Organometallics; Vol. 24; No. 11; 2789-2794; 10.1021/om058002l
• Heyduk, Alan F. and Driver, Tom G., et el. (2004) Kinetic and Thermodynamic Preferences in Aryl vs Benzylic C−H Bond Activation with Cationic Pt(II) Complexes; Journal of the American Chemical Society; Vol. 126; No. 46; 15034-15035; 10.1021/ja045078k
• Iverson, Carl N. and Carter, Charles A. G., et el. (2004) C-H Bond Activation with Neutral Platinum Methyl Complexes; ISBN 9780841238497; Activation and Functionalization of C—H Bonds; 319-333; 10.1021/bk-2004-0885.ch019
• Heyduk, Alan F. and Zhong, H. Annita, et el. (2004) C—H Bond Activation at Pt(II): A Route to Selective Alkane Oxidation?; ISBN 9780841238497; Activation and Functionalization of C—H Bonds; 250-263; 10.1021/bk-2004-0885.ch015
• Baar, Cliff R. and Levy, Christopher J., et el. (2004) Kinetic Resolution of Chiral α-Olefins Using Optically Active ansa-Zirconocene Polymerization Catalysts; Journal of the American Chemical Society; Vol. 126; No. 26; 8216-8231; 10.1021/ja040021j
• Owen, Jonathan S. and Labinger, Jay A., et el. (2004) Pyridinium-Derived N-Heterocyclic Carbene Complexes of Platinum: Synthesis, Structure and Ligand Substitution Kinetics; Journal of the American Chemical Society; Vol. 126; No. 26; 8247-8255; 10.1021/ja040075t
• Miller, Stephen A. and Bercaw, John E. (2004) Highly Stereoregular Syndiotactic Polypropylene Formation with Metallocene Catalysts via Influence of Distal Ligand Substituents; Organometallics; Vol. 23; No. 8; 1777-1789; 10.1021/om030333f
• Agapie, Theodor and Schofer, Susan J., et el. (2004) Mechanistic Studies of the Ethylene Trimerization Reaction with Chromium−Diphosphine Catalysts: Experimental Evidence for a Mechanism Involving Metallacyclic Intermediates; Journal of the American Chemical Society; Vol. 126; No. 5; 1304-1305; 10.1021/ja038968t
• Iverson, Carl N. and Carter, Charles A. G., et el. (2003) C−H Bond Activation by Unsymmetrical 2-(N-Arylimino)pyrrolide Pt Complexes: Geometric Effects on Reactivity; Journal of the American Chemical Society; Vol. 125; No. 42; 12674-12675; 10.1021/ja036511d
• Ackerman, Lily J. and Sadighi, Joseph P., et el. (2003) Arene C−H Bond Activation and Arene Oxidative Coupling by Cationic Palladium(II) Complexes; Organometallics; Vol. 22; No. 19; 3884-3890; 10.1021/om0303294
• Heyduk, Alan F. and Labinger, Jay A., et el. (2003) Catalytic Alcoholysis of Tetramethylsilane via Pt-Mediated C−H Bond Activation; Journal of the American Chemical Society; Vol. 125; No. 21; 6366-6367; 10.1021/ja029099v
• Chirik, Paul J. and Zubris, Deanna L., et el. (2003) Preparation of ansa-Niobocene and ansa-Tantalocene Olefin Hydride Complexes as Transition State Analogues in Metallocene-Catalyzed Olefin Polymerization; Organometallics; Vol. 22; No. 1; 172-187; 10.1021/om020628d
• Ackerman, Lily J. and Green, Malcolm L. H., et el. (2003) Experimental and Theoretical Studies of Olefin Insertion foransa-Niobocene andansa-Tantalocene Ethylene Hydride Complexes; Organometallics; Vol. 22; No. 1; 188-194; 10.1021/om0206296
• Zachmanoglou, Cary E. and Docrat, Arefa, et el. (2002) The Electronic Influence of Ring Substituents and Ansa Bridges in Zirconocene Complexes as Probed by Infrared Spectroscopic, Electrochemical, and Computational Studies; Journal of the American Chemical Society; Vol. 124; No. 32; 9525-9546; 10.1021/ja020236y
• Rostovtsev, Vsevolod V. and Henling, Lawrence M., et el. (2002) Structural and Mechanistic Investigations of the Oxidation of Dimethylplatinum(II) Complexes by Dioxygen; Inorganic Chemistry; Vol. 41; No. 14; 3608-3619; 10.1021/ic0112903
• Labinger, Jay A. and Bercaw, John E. (2002) Understanding and exploiting C–H bond activation; Nature; Vol. 417; No. 6888; 507-514; 10.1038/417507a
• Yoder, Jeffrey C. and Bercaw, John E. (2002) Chain Epimerization during Propylene Polymerization with Metallocene Catalysts: Mechanistic Studies Using a Doubly Labeled Propylene; Journal of the American Chemical Society; Vol. 124; No. 11; 2548-2555; 10.1021/ja0123296
• Miller, Stephen A. and Bercaw, John E. (2002) Isotactic−Hemiisotactic Polypropylene from C_1-Symmetric ansa-Metallocene Catalysts: A New Strategy for the Synthesis of Elastomeric Polypropylene; Organometallics; Vol. 21; No. 5; 934-945; 10.1021/om010788+
• Zhong, H. Annita and Labinger, Jay A., et el. (2002) C−H Bond Activation by Cationic Platinum(II) Complexes: Ligand Electronic and Steric Effects; Journal of the American Chemical Society; Vol. 124; No. 7; 1378-1399; 10.1021/ja011189x
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• Wendt, Ola F. and Bercaw, John E. (2001) Thermally Stable Dialkylzirconocenes with β-Hydrogens. Synthesis and Diastereoselectivity; Organometallics; Vol. 20; No. 18; 3891-3895; 10.1021/om0102910
• Scollard, John D. and Labinger, Jay A., et el. (2001) Studies towards the functionalization of light alkanes: Facile C-H bond activation by a neutral Pt(II) alkyl complex; Abstracts of Papers of the American Chemical Society; Vol. 221; INOR 85
• Zhong, Hong Annita and Labinger, Jay A., et el. (2001) Carbon-hydrogen bond activation mediated by cationic platinum(II) complexes; Abstracts of Papers of the American Chemical Society; Vol. 221; INOR 83
• Balzarek, Christoph and Labinger, Jay A., et el. (2001) Chemistry of water-soluble Pt-diimine complexes relevant to C-H bond activation; Abstracts of Papers of the American Chemical Society; Vol. 221; INOR 201
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• Miller, Stephen A. and Bercaw, John E. (2000) Aminofluorenyl−Pentamethylcyclopentadienyl and Bis(aminofluorenyl) Derivatives of Group 4 Metals; Organometallics; Vol. 19; No. 26; 5608-5613; 10.1021/om000723r
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• Stahl, Shannon S. and Labinger, Jay A., et el. (1998) Investigations of the Factors Affecting the Stability of Dihydrogen Adducts of Platinum(II); Inorganic Chemistry; Vol. 37; No. 10; 2422-2431; 10.1021/ic970944y
• Kiely, Andrew F. and Nelson, Cory M., et el. (1998) Heterolysis of H−X Bonds by Pentamethylcyclopentadienyl−Aminoborole Complexes of Zirconium and Hafnium; Organometallics; Vol. 17; No. 7; 1324-1332; 10.1021/om9709345
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• Luinstra, Gerrit A. and Labinger, Jay A., et el. (1993) Mechanism and stereochemistry for nucleophilic attack at carbon of platinum(IV) alkyls: model reactions for hydrocarbon oxidation with aqueous platinum chlorides; Journal of the American Chemical Society; Vol. 115; No. 7; 3004-3005; 10.1021/ja00060a070
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