Stoltz, Brian

Combined from CaltechAUTHORS

• Moghadam, Farbod A. and Barbor, Jay P., et el. (2024) Formation of All-Carbon Quaternary Centers via Enantioselective Pd-Catalyzed α-Vinylation of γ-Lactams; Organic Letters; Vol. 26; No. 36; 7551–7554; 10.1021/acs.orglett.4c02551
• Stanko, Allison M. and Ramirez, Melissa, et el. (2024) Enantioselective Nickel-Catalyzed α-Spirocyclization of Lactones; Organic Letters; Vol. 26; No. 32; 6793-6797; 10.1021/acs.orglett.4c01661
• Samkian, Adrian E. and Virgil, Scott C., et el. (2024) Total Synthesis of Hypersampsone M; Journal of the American Chemical Society; 10.1021/jacs.4c07007
• Ngamnithiporn, Aurapat and Welin, Eric R., et el. (2024) Evolution of a Synthetic Strategy toward the Syntheses of Bis-tetrahydroisoquinoline Alkaloids; Accounts of Chemical Research; Vol. 57; No. 13; 1870-1884; PMCID PMC11223266
• Gonzalez, Kevin J. and Cerione, Chloe, et el. (2024) Strategies for the Development of Asymmetric and Non‐Directed Petasis Reactions; Chemistry – A European Journal; e202401936; 10.1002/chem.202401936
• Chen, Peng-Jui and Cusumano, Alexander Q., et el. (2024) Molecular Dynamics Investigations of Dienolate [4 + 2] Reactions; Journal of the American Chemical Society; Vol. 146; No. 18; 12758-12765; PMCID PMC11082897; 10.1021/jacs.4c02681
• Gross, Benjamin M. and Stoltz, Brian M. (2024) Convenient access to a strained bicyclic enone: A concise and improved formal synthesis of ineleganolide; Tetrahedron Letters; Vol. 140; 155011; 10.1016/j.tetlet.2024.155011
• Hicks, Elliot F. and Inoue, Kengo, et el. (2024) Enantioselective Total Synthesis of (−)-Hunterine A Enabled by a Desymmetrization/Rearrangement Strategy; Journal of the American Chemical Society; Vol. 146; No. 7; 4340-4345; PMCID PMC10885145; 10.1021/jacs.3c13590
• Xu, Yinchao and Stanko, Allison M., et el. (2024) Low Part-Per-Trillion, Humidity Resistant Detection of Nitric Oxide Using Microtoroid Optical Resonators; ACS Applied Materials & Interfaces; Vol. 16; No. 4; 5120-5128; 10.1021/acsami.3c16012
• Yu, Hao and Sercel, Zachary P., et el. (2023) Total Synthesis of Aleutianamine; Journal of the American Chemical Society; Vol. 145; No. 47; 25533-25537; PMCID PMC10690800; 10.1021/jacs.3c10212
• Stoltz, Brian M. (2023) Editorial for special issue in honor of Professor John Wood; Tetrahedron; Vol. 148; 133700; 10.1016/j.tet.2023.133700
• Nishiura, Yuji and Gonzalez, Kevin J., et el. (2023) Enantioselective 1,3-Dipolar Cycloadditions of α-Methylene Lactams to Construct Spirocycles; Organic Letters; Vol. 25; No. 35; 6469-6473; PMCID PMC10496134; 10.1021/acs.orglett.3c01978
• Zhang, Tianyi and Nishiura, Yuji, et el. (2023) Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to α,β-Unsaturated Lactams: Enantioselective Construction of All-Carbon Quaternary Stereocenters in Saturated Nitrogen-Containing Heterocycles; Organic Letters; Vol. 25; No. 35; 6479-6484; PMCID PMC10496148; 10.1021/acs.orglett.3c02064
• Cusumano, Alexander and Zhang, Tianyi, et el. (2023) Origins of Enhanced Enantioselectivity in the Pd-Catalyzed Decarboxylative Allylic Alkylation of N-Benzoyl Lactams; Catalysts; Vol. 13; No. 9; 1258; PMCID PMC10662798; 10.3390/catal13091258
• Kim, Alexia N. and Ngamnithiporn, Aurapat, et el. (2023) Recent Advances in the Total Synthesis of the Tetrahydroisoquinoline Alkaloids (2002–2020); Chemical Reviews; Vol. 123; No. 15; 9447-9496; PMCID PMC10416225; 10.1021/acs.chemrev.3c00054
• Barbor, Jay P. and Nair, Vaishnavi N., et el. (2023) Development of a Nickel-Catalyzed N–N Coupling for the Synthesis of Hydrazides; Journal of the American Chemical Society; Vol. 145; No. 28; 15071-15077; PMCID PMC10360072; 10.1021/jacs.3c04834
• Greßies, Steffen and Süße, Lars, et el. (2023) Tandem Dearomatization/Enantioselective Allylic Alkylation of Pyridines; Journal of the American Chemical Society; Vol. 145; No. 22; 11907-11913; PMCID PMC10251512; 10.1021/jacs.3c02470
• Flesch, Kaylin N. and Cusumano, Alexander Q., et el. (2023) Divergent Catalysis: Catalytic Asymmetric [4+2] Cycloaddition of Palladium Enolates; Journal of the American Chemical Society; Vol. 145; No. 20; 11301-11310; PMCID PMC10388310; 10.1021/jacs.3c02104
• Hafeman, Nicholas J. and Loskot, Steven A., et el. (2023) Total synthesis of (−)-scabrolide A and (−)-yonarolide; Chemical Science; Vol. 14; No. 18; 4745-4758; PMCID PMC10173254; 10.1039/d3sc00651d
• Murphy, Sara E. and Crounse, John D., et el. (2023) Accretion product formation in the self-reaction of ethene-derived hydroxy peroxy radicals; Environmental Science: Atmospheres; 10.1039/d3ea00020f
• Gross, Benjamin M. and Han, Seojung, et el. (2023) A Convergent Total Synthesis of (+)-Ineleganolide; Journal of the American Chemical Society; Vol. 145; No. 14; 7763-7767; PMCID PMC10544024; 10.1021/jacs.3c02142
• Gross, Benjamin M. and Han, Seo-Jung, et el. (2023) A Convergent Total Synthesis of (+)-Ineleganolide; Journal of the American Chemical Society; Vol. 145; No. 14; 7763-7767; 10.1021/jacs.3c02142
• Rand, Alexander W. and Gonzalez, Kevin J., et el. (2023) Total Synthesis of Strempeliopidine and Non-Natural Stereoisomers through a Convergent Petasis Borono-Mannich Reaction; Journal of the American Chemical Society; Vol. 145; No. 13; 7278-7287; PMCID PMC10281614; 10.1021/jacs.2c13146
• Gonzalez, Kevin J. and Rand, Alexander W., et el. (2023) Development of a Non‐Directed Petasis‐Type Reaction by an Aromaticity‐Disrupting Strategy; Angewandte Chemie International Edition; Vol. 62; No. 14; e202218921; PMCID PMC10033435
• Reimann, Christopher E. and Kim, Kelly E., et el. (2023) What is a cross-coupling? An argument for a universal definition; Tetrahedron; Vol. 130; 133176; PMCID PMC9878734; 10.1016/j.tet.2022.133176
• Hafeman, Nicholas J. and Chan, Melinda, et el. (2022) Asymmetric Total Synthesis of Havellockate; Journal of the American Chemical Society; Vol. 144; No. 44; 20232-20236; PMCID PMC9997676; 10.1021/jacs.2c09583
• Zhang, Tianyi and Cusumano, Alexander Q., et el. (2022) Investigations of an Unexpected [2+2] Photocycloaddition in the Synthesis of (−)-Scabrolide A from Quantum Mechanics Calculations; Journal of Organic Chemistry; Vol. 87; No. 21; 14115-14124; 10.1021/acs.joc.2c01693
• Goldstein, Elizabeth L. and Takada, Hirokazu, et el. (2022) Synthesis of enantioenriched 2,2-disubstituted pyrrolidines via sequential asymmetric allylic alkylation and ring contraction; Tetrahedron; Vol. 123; Art. No. 132940; PMCID PMC10038171; 10.1016/j.tet.2022.132940
• Fulton, Tyler J. and Du, Yun E., et el. (2022) Asymmetric allylic alkylation, allylation, and related reactions; ISBN 9781119736424; Catalytic Asymmetric Synthesis, Fourth Edition; 661-704; 10.1002/9781119736424.ch17
• Moghadam, Farbod A. and Hicks, Elliot F., et el. (2022) Ir-Catalyzed Asymmetric Allylic Alkylation of Dialkyl Malonates Enabling the Construction of Enantioenriched All-Carbon Quaternary Centers; Journal of the American Chemical Society; Vol. 144; No. 18; 7983-7987; 10.1021/jacs.2c02960
• Li, Cheng and Lohrey, Trevor D., et el. (2022) Part-per-trillion trace selective gas detection using frequency locked whispering gallery mode microtoroids; 10.26434/chemrxiv-2022-606xv
• Kim, Alexia N. and Ngamnithiporn, Aurapat, et el. (2022) Iridium-catalyzed asymmetric trans-selective hydrogenation of 1,3-disubstituted isoquinolines; Chemical Science; Vol. 13; No. 11; 3227-3232; PMCID PMC8926345; 10.1039/d1sc06729j
• Moghadam, Farbod A. and Hicks, Elliot F., et el. (2022) Ir-Catalyzed Asymmetric Allylic Alkylation of Dialkyl Malo-nates Enabling the Construction of Enantioenriched All-Carbon Quaternary Centers; 10.26434/chemrxiv-2022-n4bsw
• Chimiak, L. and Eiler, J., et el. (2022) Isotope effects at the origin of life: Fingerprints of the Strecker synthesis; Geochimica et Cosmochimica Acta; Vol. 321; 78-98; 10.1016/j.gca.2022.01.015
• Samkian, Adrian E. and Sercel, Zachary P., et el. (2022) Some unusual transformations of a highly reactive α-bromocaranone; Tetrahedron Letters; Vol. 89; Art. No. 153496; 10.1016/j.tetlet.2021.153496
• Kim, Kelly E. and Kim, Alexia N., et el. (2021) Late-Stage Diversification: A Motivating Force in Organic Synthesis; Journal of the American Chemical Society; Vol. 143; No. 41; 16890-16901; PMCID PMC9285880; 10.1021/jacs.1c08920
• Sercel, Zachary P. and Sun, Alexander W., et el. (2021) Synthesis of Enantioenriched gem-Disubstituted 4-Imidazolidinones by Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation; Organic Letters; Vol. 23; No. 16; 6348-6351; PMCID PMC8534816; 10.1021/acs.orglett.1c02134
• Lohrey, Trevor D. and Cusumano, Alexander Q., et el. (2021) Identifying the Imperative Role of Metal–Olefin Interactions in Catalytic C–O Reductive Elimination from Nickel(II); ACS Catalysis; Vol. 11; No. 16; 10208-10222; PMCID PMC8849544; 10.1021/acscatal.1c02790
• Reimann, Christopher E. and Ngamnithiporn, Aurapat, et el. (2021) The Enantioselective Synthesis of Eburnamonine, Eucophylline, and 16′-epi-Leucophyllidine; Angewandte Chemie International Edition; Vol. 60; No. 33; 17957-17962; PMCID PMC8338904; 10.1002/anie.202106184
• Cusumano, Alexander and Goddard, William Andrew, et el. (2021) Reductive elimination from palladium(II) via a [π2s + π2s + σ2s + σ2s] pericyclic reaction
• Cusumano, Alexander Q. and Houk, K. N., et el. (2021) Synthetic strategy toward ineleganolide: A cautionary tale; Tetrahedron; Vol. 93; Art. No. 132289; PMCID PMC8294177; 10.1016/j.tet.2021.132289
• Yu, Donna D. and Van Citters, Gregg, et el. (2021) Discovery of novel modulators for the PPARα (peroxisome proliferator activated receptor α): Potential therapies for nonalcoholic fatty liver disease; Bioorganic and Medicinal Chemistry; Vol. 41; Art. No. 116193; 10.1016/j.bmc.2021.116193
• Han, Seo-Jung and Cavitt, Marchello A., et el. (2021) A Synthetic Strategy toward Eight-Membered Cyclic Amines by Cycloetherification and Claisen Rearrangement; Organic Letters; Vol. 23; No. 9; 3300-3303; PMCID PMC8846577; 10.1021/acs.orglett.1c00763
• Süsse, Lars and Stoltz, Brian M. (2021) Enantioselective Formation of Quaternary Centers by Allylic Alkylation with First-Row Transition-Metal Catalysts; Chemical Reviews; Vol. 121; No. 7; 4084-4099; PMCID PMC8846597; 10.1021/acs.chemrev.0c01115
• Zhang, Gang and Li, Shan, et el. (2021) A covalent p97/VCP ATPase inhibitor can overcome resistance to CB-5083 and NMS-873 in colorectal cancer cells; European Journal of Medicinal Chemistry; Vol. 213; Art. No. 113148; PMCID PMC7954469; 10.1016/j.ejmech.2020.113148
• Li, Cheng and Lohrey, Trevor, et el. (2021) Part-per-trillion trace gas detection using frequency-locked whispering gallery mode microtoroids; ISBN 9781510642133; Integrated Optics: Devices, Materials, and Technologies XXV; Art. No. 116890B; 10.1117/12.2578032
• Sardini, Stephen R. and Stoltz, Brian M. (2021) Discussion Addendum for: Preparation of (S)-tert-ButylPyOx and Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids; Organic Syntheses; Vol. 98; 117-130; PMCID PMC9558615; 10.15227/orgsyn.098.0117
• Fulton, Tyler J. and Cusumano, Alexander Q., et el. (2020) Global Diastereoconvergence in the Ireland–Claisen Rearrangement of Isomeric Enolates: Synthesis of Tetrasubstituted α-Amino Acids; Journal of the American Chemical Society; Vol. 142; No. 52; 21938-21947; PMCID PMC8552564; 10.1021/jacs.0c11480
• Kim, Kelly E. and Sakazaki, Yuka, et el. (2020) Synthesis of non-natural cyanthiwigin–gagunin hybrids through late-stage diversification of the cyanthiwigin natural product core; Tetrahedron; Vol. 76; No. 51; Art. No. 130755; 10.1016/j.tet.2019.130755
• Kim, Alexia N. and Stoltz, Brian M. (2020) Recent Advances in Homogeneous Catalysts for the Asymmetric Hydrogenation of Heteroarenes; ACS Catalysis; Vol. 10; No. 23; 13834-13851; PMCID PMC8460131; 10.1021/acscatal.0c03958
• Cusumano, Alexander Q. and Goddard, William A., III, et el. (2020) Transition Metal Catalyzed [π2s + π2s + σ2s + σ2s] Pericyclic Reaction: Woodward–Hoffmann Rules, Aromaticity, and Electron Flow; Journal of the American Chemical Society; Vol. 142; No. 45; 19033-19039; PMCID PMC8549492; 10.1021/jacs.0c09575
• Ngamnithiporn, Aurapat and Iwayama, Toshihiko, et el. (2020) Enantioselective synthesis of highly oxygenated acyclic quaternary center-containing building blocks via palladium-catalyzed decarboxylative allylic alkylation of cyclic siloxyketones; Chemical Science; Vol. 11; No. 40; 11068-11071; PMCID PMC8162308; 10.1039/d0sc04383d
• Fulton, Tyler J. and Chen, Anthony Y., et el. (2020) Enantioselective Total Synthesis of (–)-Myrifabral A and B; Chemical Science; Vol. 11; No. 39; 10802-10806; PMCID PMC8162428; 10.1039/d0sc01141j
• Kenseth, Christopher M. and Hafeman, Nicholas J., et el. (2020) Synthesis of Carboxylic Acid and Dimer Ester Surrogates to Constrain the Abundance and Distribution of Molecular Products in α-Pinene and β-Pinene Secondary Organic Aerosol; Environmental Science and Technology; Vol. 54; No. 20; 12829-12839; 10.1021/acs.est.0c01566
• Wolf, William J. and Li, Jiaming, et el. (2020) Efficient Synthesis of Geminal-Dialkyl Dienes for Olefin Metathesis Polymerization; Macromolecules; Vol. 53; No. 18; 7803-7809; PMCID PMC8297823; 10.1021/acs.macromol.0c01606
• Cusumano, Alexander Q. and Stoltz, Brian M., et el. (2020) Reaction Mechanism, Origins of Enantioselectivity, and Reactivity Trends in Asymmetric Allylic Alkylation: A Comprehensive Quantum Mechanics Investigation of a C(sp³)–C(sp³) Cross-Coupling; Journal of the American Chemical Society; Vol. 142; No. 32; 13917-13933; PMCID PMC7802888; 10.1021/jacs.0c06243
• Kenseth, Christopher M. and Hafeman, Nicholas J., et el. (2020) Synthesis of carboxylic acid and dimer ester surrogates to constrain the abundance and distribution of molecular products in α-pinene and β-pinene secondary organic aerosol
• Inanaga, Kazato and Wollenburg, Marco, et el. (2020) Catalytic enantioselective synthesis of carbocyclic and heterocyclic spiranes via a decarboxylative aldol cyclization; Chemical Science; Vol. 11; No. 28; 7390-7395; PMCID PMC7574022; 10.1039/d0sc02366c
• Duquette, Douglas C. and Cusumano, Alexander Q., et el. (2020) Probing Trends in Enantioinduction via Substrate Design: Palladium-Catalyzed Decarboxylative Allylic Alkylation of α-Enaminones; Organic Letters; Vol. 22; No. 13; 4966-4969; PMCID PMC7608880; 10.1021/acs.orglett.0c01441
• Lavernhe, Rémi and Alexy, Eric J., et el. (2020) Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Acyclic α-N-Pyrrolyl/Indolyl Ketones; Organic Letters; Vol. 22; No. 11; 4272-4275; PMCID PMC7608871; 10.1021/acs.orglett.0c01303
• Baek, Doohyun and Ryu, Huijeong, et el. (2020) Catalytic enantioselective synthesis of tetrasubstituted chromanones via palladium-catalyzed asymmetric conjugate arylation using chiral pyridine-dihydroisoquinoline ligands; Chemical Science; Vol. 11; No. 18; 4602-4607; PMCID PMC7574023; 10.1039/d0sc00412j
• Hafeman, Nicholas J. and Loskot, Steven A., et el. (2020) The Total Synthesis of (–)-Scabrolide A; Journal of the American Chemical Society; Vol. 142; No. 19; 8585-8590; 10.1021/jacs.0c02513
• Kim, Alexia N. and Ngamnithiporn, Aurapat, et el. (2020) Iridium-Catalyzed Enantioselective and Diastereoselective Hydrogenation of 1,3-Disubstituted Isoquinolines; ACS Catalysis; Vol. 10; No. 5; 3241-3248; PMCID PMC8152574; 10.1021/acscatal.0c00211
• Jette, Carina I. and Tong, Z. Jaron, et el. (2020) Copper-Catalyzed Enantioselective Allylic Alkylation with a γ-Butyrolactone-Derived Silyl Ketene Acetal; Angewandte Chemie International Edition; Vol. 59; No. 5; 2033-2038; PMCID PMC7051182; 10.1002/anie.201912618
• Lavernhe, Rémi and Alexy, Eric J., et el. (2020) Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Protected Benzoin-Derived Enol Carbonates; Advanced Synthesis and Catalysis; Vol. 362; No. 2; 344-347; PMCID PMC7942817; 10.1002/adsc.201901281
• Park, Dongseong and Jette, Carina I., et el. (2020) Enantioselective Alkynylation of Trifluoromethyl Ketones Catalyzed by Cation-Binding Salen Nickel Complexes; Angewandte Chemie International Edition; Vol. 59; No. 2; 775-779; 10.1002/anie.201913057
• Li, Jiaming and Stoltz, Brian M., et el. (2019) Enantioselective Synthesis of 15-Deoxy-Δ¹²,¹⁴-Prostaglandin J₂; Organic Letters; Vol. 21; No. 24; 10139-10142; 10.1021/acs.orglett.9b04198
• Wright, Austin C. and Stoltz, Brian M. (2019) Enantioselective construction of the tricyclic core of curcusones A–D via a cross-electrophile coupling approach; Chemical Science; Vol. 10; No. 45; 10562-10565; PMCID PMC6988747; 10.1039/c9sc04127c
• Wright, Austin C. and Lee, Chung Whan, et el. (2019) Progress toward the Enantioselective Synthesis of Curcusones A–D via a Divinylcyclopropane Rearrangement Strategy; Organic Letters; Vol. 21; No. 23; 9658-9662; 10.1021/acs.orglett.9b03829
• Sercel, Zachary P. and Sun, Alexander W., et el. (2019) Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of 1,4-Diazepan-5-ones; Organic Letters; Vol. 21; No. 22; 9158-9161; PMCID PMC8579948; 10.1021/acs.orglett.9b03530
• Velasco-Rubio, Álvaro and Alexy, Eric J., et el. (2019) Stereospecific Overman Rearrangement of Substituted Cyclic Vinyl Bromides: Access to Fully Substituted α-Amino Ketones; Organic Letters; Vol. 21; No. 22; 8962-8965; 10.1021/acs.orglett.9b03347
• Schuman, David P. and Liu, Wen‐Bo, et el. (2019) Transition‐Metal‐Free Catalytic C─H Bond Silylation; ISBN 9783527344536; Organosilicon Chemistry: Novel Approaches and Reactions; 213-240; 10.1002/9783527814787.ch7
• Sun, Alexander W. and Lackner, Sebastian, et el. (2019) Modularity: Adding New Dimensions to Total Synthesis; Trends in Chemistry; Vol. 1; No. 7; 630-643; 10.1016/j.trechm.2019.05.008
• Jones, Christopher G. and Asay, Matthew, et el. (2019) Characterization of Reactive Organometallic Species via MicroED; ACS Central Science; Vol. 5; No. 9; 1507-1513; PMCID PMC6764211; 10.1021/acscentsci.9b00403
• Sun, Alexander W. and Bulterys, Philip L., et el. (2019) Incorporation of a chiral gem-disubstituted nitrogen heterocycle yields an oxazolidinone antibiotic with reduced mitochondrial toxicity; Bioorganic and Medicinal Chemistry Letters; Vol. 29; No. 18; 2686-2689; PMCID PMC6711789; 10.1016/j.bmcl.2019.07.024
• Wright, Austin C. and Du, Yun Emily, et el. (2019) A Small-scale Procedure for Acid-catalyzed Ketal Formation; Journal of Organic Chemistry; Vol. 84; No. 17; 11258-11260; 10.1021/acs.joc.9b01541
• Fulton, Tyler J. and Wu, Brenda, et el. (2019) Palladium-catalyzed α,β-dehydrogenation of acyclic ester equivalents promoted by a novel electron deficient phosphinooxazoline ligand; Tetrahedron; Vol. 75; No. 31; 4104-4109; PMCID PMC7119178; 10.1016/j.tet.2019.05.065
• Craig, Robert A., II and Smith, Russell C., et el. (2019) Unified Enantioselective, Convergent Synthetic Approach Toward the Furanobutenolide-Derived Polycyclic Norcembranoid Diterpenes: Synthesis of a Series of Ineleganoloids by Oxidation State Manipulation of the Carbocyclic Core; Journal of Organic Chemistry; Vol. 84; No. 12; 7722-7746; 10.1021/acs.joc.9b00635
• Alexy, Eric J. and Fulton, Tyler J., et el. (2019) Palladium-catalyzed enantioselective decarboxylative allylic alkylation of fully substituted N-acyl indole-derived enol carbonates; Chemical Science; Vol. 10; No. 23; 5996-6000; PMCID PMC6566452; 10.1039/c9sc01726g
• Harned, Andrew M. and Stoltz, Brian M. (2019) Development of a catalytic enantioselective synthesis of the guanacastepene and heptemerone tricyclic core; Tetrahedron; Vol. 75; No. 24; 3166-3177; PMCID PMC6959853; 10.1016/j.tet.2019.02.053
• Lee, Chung Whan and Taylor, Buck L. H., et el. (2019) An unexpected Ireland–Claisen rearrangement cascade during the synthesis of the tricyclic core of Curcusone C: Mechanistic elucidation by trial-and-error and automatic artificial force-induced reaction (AFIR) computations; Journal of the American Chemical Society; Vol. 141; No. 17; 6995-7004; 10.1021/jacs.9b01146
• Wright, Austin C. and Stoltz, Brian M. (2019) Discussion Addendum for: The Direct Acyl-Alkylation of Arynes. Preparation of Methyl 2-(2-acetylphenyl)acetate; Organic Syntheses; Vol. 96; 80-97
• Yamano, Michael M. and Knapp, Rachel R., et el. (2019) Cycloadditions of Oxacyclic Allenes and a Catalytic Asymmetric Entryway to Enantioenriched Cyclic Allenes; Angewandte Chemie International Edition; Vol. 58; No. 17; 5653-5657; PMCID PMC6456397; 10.1002/anie.201900503
• Sun, Alexander W. and Stoltz, Brian M. (2019) Discussion Addendum for: Preparation of (S)-tert-ButylPHOX and (S)-2-Allyl-2-Methylcyclohexanone; ISBN 9780471264224; Organic Syntheses; 10.1002/0471264229.os095.29
• Sun, Alexander and Stoltz, Brian Mark (2019) Enantioselective synthesis of gem-disubstituted N-Boc diazaheterocycles via decarboxylative asymmetric allylic alkylation
• Jette, Carina I. and Geibel, Irina, et el. (2019) Palladium-Catalyzed Construction of Quaternary Stereocenters by Enantioselective Arylation of γ-Lactams with Aryl Chlorides and Bromides; Angewandte Chemie International Edition; Vol. 58; No. 13; 4297-4301; 10.1002/anie.201814475
• Han, Seo-Jung and Bhat, Vikram, et el. (2019) Atroposelective Synthesis of PINAP via Dynamic Kinetic Asymmetric Transformation; Advanced Synthesis and Catalysis; Vol. 361; No. 3; 441-444; 10.1002/adsc.201801248
• Sun, Alexander W. and Hess, Stephan N., et el. (2019) Enantioselective synthesis of gem-disubstituted N-Boc diazaheterocycles via decarboxylative asymmetric allylic alkylation; Chemical Science; Vol. 10; No. 3; 788-792; PMCID PMC6345351; 10.1039/c8sc03967d
• Welin, Eric R. and Ngamnithiporn, Aurapat, et el. (2019) Concise total syntheses of (–)-jorunnamycin A and (–)-jorumycin enabled by asymmetric catalysis; Science; Vol. 363; No. 6424; 270-275; PMCID PMC7017906; 10.1126/science.aav3421
• Praske, Eric and Otkjær, Rasmus V., et el. (2019) Intramolecular Hydrogen Shift Chemistry of Hydroperoxy-Substituted Peroxy Radicals; Journal of Physical Chemistry A; Vol. 123; No. 2; 590-600; 10.1021/acs.jpca.8b09745
• Li, Jiaming and Ahmed, Tonia S., et el. (2019) Concise Syntheses of Δ^(12)-Prostaglandin J Natural Products via Stereoretentive Metathesis; Journal of the American Chemical Society; Vol. 141; No. 1; 154-158; 10.1021/jacs.8b12816
• Shockley, Samantha E. and Hethcox, J. Caleb, et el. (2018) Intermolecular Stereoselective Iridium-Catalyzed Allylic Alkylation: An Evolutionary Account; Synlett; Vol. 29; No. 19; 2481-2492; PMCID PMC6870865; 10.1055/s-0037-1610217
• Jones, Christopher G. and Martynowycz, Michael W., et el. (2018) The CryoEM Method MicroED as a Powerful Tool for Small Molecule Structure Determination; ACS Central Science; Vol. 4; No. 11; 1587-1592; PMCID PMC6276044; 10.1021/acscentsci.8b00760
• Davies, Huw M. L. and Itami, Kenichiro, et el. (2018) New directions in natural product synthesis; Chemical Society Reviews; Vol. 47; No. 21; 7828-7829; 10.1039/c8cs90115e
• Liu, Wenbin and Ren, Zhi, et el. (2018) Catalyst-Controlled Selective Functionalization of Unactivated C–H Bonds in the Presence of Electronically Activated C–H Bonds; Journal of the American Chemical Society; Vol. 140; No. 38; 12247-12255; 10.1021/jacs.8b07534
• Lu, Yanhui and Goldstein, Elizabeth L., et el. (2018) Palladium-Catalyzed Enantioselective C_(sp)^3–C_(sp)^3 Cross-Coupling for the Synthesis of (Poly)fluorinated Chiral Building Blocks; Organic Letters; Vol. 20; No. 18; 5657-5660; PMCID PMC6192028; 10.1021/acs.orglett.8b02369
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• Ly, Tony and Krout, Michael, et el. (2007) Synthesis of 2-Quinuclidonium by Eliminating Water: Experimental Quantification of the High Basicity of Extremely Twisted Amides; Journal of the American Chemical Society; Vol. 129; No. 7; 1864-1865; 10.1021/ja067703m
• Ferreira, Eric M. and Stoltz, Brian M. (2006) The synthesis of C-3β functionalized indoles via a hydroboration/Suzuki–Miyaura coupling sequence; Tetrahedron Letters; Vol. 47; No. 48; 8579-8582; PMCID PMC1832155; 10.1016/j.tetlet.2006.09.112
• Tambar, Uttam K. and Kano, Taichi, et el. (2006) Convergent and Diastereoselective Synthesis of the Polycyclic Pyran Core of Saudin; Journal of Organic Chemistry; Vol. 71; No. 22; 8357-8364; 10.1021/jo061236+
• Garg, Neil K. and Stoltz, Brian M. (2006) A unified synthetic approach to the pyrazinone dragmacidins; Chemical Communications; Vol. 2006; No. 36; 3769-3779; 10.1039/b605929e
• Tambar, Uttam K. and Ebner, David C., et el. (2006) A Convergent and Enantioselective Synthesis of (+)-Amurensinine via Selective C−H and C−C Bond Insertion Reactions; Journal of the American Chemical Society; Vol. 128; No. 36; 11752-11753; PMCID PMC2529249; 10.1021/ja0651815
• Mohr, Justin T. and Nishimata, Toyoki, et el. (2006) Catalytic Enantioselective Decarboxylative Protonation; Journal of the American Chemical Society; Vol. 128; No. 35; 11348-11349; 10.1021/ja063335a
• McFadden, Ryan M. and Stoltz, Brian M. (2006) The Catalytic Enantioselective, Protecting Group-Free Total Synthesis of (+)-Dichroanone; Journal of the American Chemical Society; Vol. 128; No. 24; 7738-7739; 10.1021/ja061853f
• Tani, Kousuke and Stoltz, Brian M. (2006) Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate; Nature; Vol. 441; No. 7094; 731-734; 10.1038/nature04842
• Meyer, Michael E. and Ferreira, Eric M., et el. (2006) 2-Diazoacetoacetic acid, an efficient and convenient reagent for the synthesis of alpha-diazo-beta-ketoesters; Chemical Communications; Vol. 2006; No. 12; 1316-1318; 10.1039/b517719g
• Lacenere, Christopher J. and Garg, Neil K., et el. (2006) Effects of a Modified Dye-Labeled Nucleotide Spacer Arm on Incorporation by Thermophilic DNA Polymerases; Nucleosides, Nucleotides and Nucleic Acids; Vol. 25; No. 1; 9-15; 10.1080/15257770500377714
• Trend, Raissa M. and Ramtohul, Yeeman K., et el. (2005) Oxidative Cyclizations in a Nonpolar Solvent Using Molecular Oxygen and Studies on the Stereochemistry of Oxypalladation; Journal of the American Chemical Society; Vol. 127; No. 50; 17778-17788; PMCID PMC2585987; 10.1021/ja055534k
• Mohr, Justin T. and Behenna, Douglas C., et el. (2005) Deracemization of Quaternary Stereocenters by Pd-Catalyzed Enantioconvergent Decarboxylative Allylation of Racemic β-Ketoesters; Angewandte Chemie International Edition; Vol. 44; No. 42; 6924-6927; 10.1002/anie.200502018
• Caspi, Daniel D. and Garg, Neil K., et el. (2005) Heterogeneous Reductive Isomerization Reaction Using Catalytic Pd/C and H_2; Organic Letters; Vol. 7; No. 12; 2513-2516; 10.1021/ol050952f
• Tambar, Uttam K. and Kano, Taichi, et el. (2005) Progress toward the Total Synthesis of Saudin: Development of a Tandem Stille-Oxa-Electrocyclization Reaction; Organic Letters; Vol. 7; No. 12; 2413-2416; 10.1021/ol050705b
• Garg, Neil K. and Caspi, Daniel D., et el. (2005) Development of an Enantiodivergent Strategy for the Total Synthesis of (+)- and (−)-Dragmacidin F from a Single Enantiomer of Quinic Acid; Journal of the American Chemical Society; Vol. 127; No. 16; 5970-5978; 10.1021/ja050586v
• Tambar, Uttam K. and Stoltz, Brian M. (2005) The Direct Acyl-Alkylation of Arynes; Journal of the American Chemical Society; Vol. 127; No. 15; 5340-5341; 10.1021/ja050859m
• Garg, Neil K. and Woodroofe, Carolyn C., et el. (2005) A ligand-free solid-supported system for Sonogashira couplings: applications in nucleoside chemistry; Chemical Communications; Vol. 2005; No. 36; 4551-4553; 10.1039/b505737j
• Behenna, Douglas C. and Stoltz, Brian M. (2004) The Enantioselective Tsuji Allylation; Journal of the American Chemical Society; Vol. 126; No. 46; 15044-15045; 10.1021/ja044812x
• Behenna, Douglas C. and Stoltz, Brian M. (2004) The Enantioselective Tsuji Allylation; Journal of the American Chemical Society; Vol. 126; No. 46; 15044-15045; 10.1021/ja044812x
• Zhang, Haiming and Ferreira, Eric M., et el. (2004) Direct Oxidative Heck Cyclizations: Intramolecular Fujiwara-Moritani Arylations for the Synthesis of Functionalized Benzofurans and Dihydrobenzofurans; Angewandte Chemie International Edition; Vol. 43; No. 45; 6144-6148; 10.1002/anie.200461294
• Garg, Neil K. and Caspi, Daniel D., et el. (2004) The Total Synthesis of (+)-Dragmacidin F; Journal of the American Chemical Society; Vol. 126; No. 31; 9552-9553; 10.1021/ja046695b
• Nielsen, Robert J. and Keith, Jason M., et el. (2004) A Computational Model Relating Structure and Reactivity in Enantioselective Oxidations of Secondary Alcohols by (−)-Sparteine−Pd^(II) Complexes; Journal of the American Chemical Society; Vol. 126; No. 25; 7967-7974; 10.1021/ja031911m
• Trend, Raissa M. and Stoltz, Brian M. (2004) An Experimentally Derived Model for Stereoselectivity in the Aerobic Oxidative Kinetic Resolution of Secondary Alcohols by (Sparteine)PdCl_2; Journal of the American Chemical Society; Vol. 126; No. 14; 4482-4483; 10.1021/ja039551q
• Su, Julius T. and Sarpong, Richmond, et el. (2004) Substituent Effects and Nearly Degenerate Transition States: Rational Design of Substrates for the Tandem Wolff−Cope Reaction; Journal of the American Chemical Society; Vol. 126; No. 1; 24-25; 10.1021/ja037716p
• Bagdanoff, Jeffrey T. and Stoltz, Brian M. (2004) Palladium-Catalyzed Oxidative Kinetic Resolution with Ambient Air as the Stoichiometric Oxidation Gas; Angewandte Chemie International Edition; Vol. 43; No. 3; 353-357; 10.1002/anie.200352444
• Ashley, Eric R. and Cruz, Ernest G., et el. (2003) The Total Synthesis of (−)-Lemonomycin; Journal of the American Chemical Society; Vol. 125; No. 49; 15000-15001; 10.1021/ja039223q
• Sarpong, Richmond and Su, Julius T., et el. (2003) The Development of a Facile Tandem Wolff/Cope Rearrangement for the Synthesis of Fused Carbocyclic Skeletons; Journal of the American Chemical Society; Vol. 125; No. 45; 13624-13625; 10.1021/ja037587c
• Ferreira, Eric M. and Stoltz, Brian M. (2003) Catalytic C−H Bond Functionalization with Palladium(II): Aerobic Oxidative Annulations of Indoles; Journal of the American Chemical Society; Vol. 125; No. 32; 9578-9579; 10.1021/ja035054y
• Trend, Raissa M. and Ramtohul, Yeeman K., et el. (2003) Palladium-Catalyzed Oxidative Wacker Cyclizations in Nonpolar Organic Solvents with Molecular Oxygen: A Stepping Stone to Asymmetric Aerobic Cyclizations; Angewandte Chemie International Edition; Vol. 42; No. 25; 2892-2895; 10.1002/anie.200351196
• Julian, Ryan R. and May, Jeremy A., et el. (2003) Gas-Phase Synthesis of Charged Copper and Silver Fischer Carbenes from Diazomalonates: Mechanistic and Conformational Considerations in Metal-Mediated Wolff Rearrangements; Journal of the American Chemical Society; Vol. 125; No. 15; 4478-4486; 10.1021/ja028337j
• Bagdanoff, Jeffrey T. and Ferreira, Eric M., et el. (2003) Palladium-Catalyzed Enantioselective Oxidation of Alcohols: A Dramatic Rate Acceleration by Cs_2CO_3/t-BuOH; Organic Letters; Vol. 5; No. 6; 835-837; 10.1021/ol027463p
• Julian, Ryan R. and May, Jeremy A., et el. (2003) Molecular Mousetraps: Gas-Phase Studies of the Covalent Coupling of Noncovalent Complexes Initiated by Reactive Carbenes Formed by Controlled Activation of Diazo Precursors; Angewandte Chemie International Edition; Vol. 42; No. 9; 1012-1015; 10.1002/anie.200390258
• Garg, Neil K. and Sarpong, Richmond, et el. (2002) The First Total Synthesis of Dragmacidin D; Journal of the American Chemical Society; Vol. 124; No. 44; 13179-13184; 10.1021/ja027822b
• May, Jeremy A. and Stoltz, Brian M. (2002) Non-Carbonyl-Stabilized Metallocarbenoids in Synthesis: The Development of a Tandem Rhodium-Catalyzed Bamford−Stevens/Thermal Aliphatic Claisen Rearrangement Sequence; Journal of the American Chemical Society; Vol. 124; No. 42; 12426-12427; 10.1021/ja028020j
• Spessard, Sarah J. and Stoltz, Brian M. (2002) Progress toward the Synthesis of Garsubellin A and Related Phloroglucins: The Direct Diastereoselective Synthesis of the Bicyclo[3.3.1]nonane Core; Organic Letters; Vol. 4; No. 11; 1943-1946; 10.1021/ol025968+
• Ferreira, Eric M. and Stoltz, Brian M. (2001) The Palladium-Catalyzed Oxidative Kinetic Resolution of Secondary Alcohols with Molecular Oxygen; Journal of the American Chemical Society; Vol. 123; No. 31; 7725-7726; 10.1021/ja015791z
• Fuerst, Douglas E. and Stoltz, Brian M., et el. (2000) Synthesis of C(3) Benzofuran-Derived Bisaryl Quaternary Centers: Approaches to Diazonamide A; Organic Letters; Vol. 2; No. 22; 3521-3523; 10.1021/ol006578v
• Ge, Min and Stoltz, Brian M., et el. (2000) Mechanistic Insights into the Factors Determining Exo−EndoSelectivity in the Lewis Acid-Catalyzed Diels−Alder Reaction of 1,3-Dienes with 2-Cycloalkenones; Organic Letters; Vol. 2; No. 13; 1927-1929; 10.1021/ol0060026